Reduction of CO2 by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate
Authors of publication
Roy, Lisa; Al-Afyouni, Malik H.; DeRosha, Daniel E.; Mondal, Bhaskar; DiMucci, Ida M.; Lancaster, Kyle M.; Shearer, Jason; Bill, Eckhard; Brennessel, William W.; Neese, Frank; Ye, Shengfa; Holland, Patrick L.
Journal of publication
Chemical Science
Year of publication
2019
a
20.919 ± 0.002 Å
b
28.234 ± 0.003 Å
c
24.42 ± 0.003 Å
α
90°
β
114.237 ± 0.002°
γ
90°
Cell volume
13152 ± 2 Å3
Cell temperature
100 ± 0.5 K
Ambient diffraction temperature
100 ± 0.5 K
Number of distinct elements
5
Space group number
9
Hermann-Mauguin space group symbol
C 1 c 1
Hall space group symbol
C -2yc
Residual factor for all reflections
0.1182
Residual factor for significantly intense reflections
0.0603
Weighted residual factors for significantly intense reflections
0.1053
Weighted residual factors for all reflections included in the refinement
0.126
Goodness-of-fit parameter for all reflections included in the refinement
