Information card for entry 1557236

Structure parameters

• Formula: C33 H48 Au Cl2 F6 N O2 P Sb
• Calculated formula: C33 H48 Au Cl2 F6 N O2 P Sb
• SMILES: c12ccccc1[N](C)(C)[Au]1([CH2]=[CH]1C(=O)OC)[P]2(C12CC3CC(C1)CC(C2)C3)C12CC3CC(CC(C1)C3)C2.C(Cl)Cl.F[Sb](F)(F)(F)(F)[F-]
• Title of publication: Versatility and adaptative behaviour of the P^N chelating ligand MeDalphos within gold(i) π complexes
• Authors of publication: Navarro, Miquel; Toledo, Alberto; Mallet-Ladeira, Sonia; Sosa Carrizo, E. Daiann; Miqueu, Karinne; Bourissou, Didier
• Journal of publication: Chemical Science
• Year of publication: 2020
• Journal volume: 11
• Journal issue: 10
• Pages of publication: 2750 - 2758
• a: 14.8546 ± 0.0012 Å
• b: 12.2517 ± 0.0009 Å
• c: 20.5946 ± 0.0016 Å
• α: 90°
• β: 99.848 ± 0.003°
• γ: 90°
• Cell volume: 3692.9 ± 0.5 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 9
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0197
• Residual factor for significantly intense reflections: 0.0192
• Weighted residual factors for significantly intense reflections: 0.0475
• Weighted residual factors for all reflections included in the refinement: 0.0478
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No