Coligand Role in the NHC Nickel catalyzed C‒F Bond Activation: Investigations on the Insertion of bis(NHC) Nickel into the C‒F Bond of Hexafluorobenzene
Authors of publication
Kuntze-Fechner, Maximilian; Holthausen, Max C C.; Marder, Todd B.; Braunschweig, Holger; Krummenacher, Ivo; Radius, Udo; Tendera, Lukas; Verplancke, Hendrik; Diefenbach, Martin
Journal of publication
Chemical Science
Year of publication
2020
a
13.8929 ± 0.0005 Å
b
10.8012 ± 0.0004 Å
c
27.4228 ± 0.0009 Å
α
90°
β
91.771 ± 0.002°
γ
90°
Cell volume
4113.1 ± 0.3 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.0527
Residual factor for significantly intense reflections
0.037
Weighted residual factors for significantly intense reflections
0.0883
Weighted residual factors for all reflections included in the refinement
0.0957
Goodness-of-fit parameter for all reflections included in the refinement
