#------------------------------------------------------------------------------
#$Date: 2021-12-10 09:55:39 +0100 (Fri 10 de Dec de 2021) $
#$Revision: 271323 $
#$URL: svn://www.crystallography.net/cod/cif/1/56/56/1565650.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1565650
loop_
_publ_author_name
'Louka, Febee R.'
'Haq, Sabriah J.'
'Guidry, Hollie R.'
'Williams, Bailey R.'
'Henary, Maher M.'
'Fischer, Roland C.'
'Torvisco, Ana'
'Massoud, Salah S.'
'Mautner, Franz A.'
_publ_section_title
;
 Polynuclear and coordination polymers of copper(II) complexes assembled
 by flexible polyamines and bridging rigid N-heterocyclic
 multicarboxylates
;
_journal_name_full               'Inorganica Chimica Acta'
_journal_page_first              119240
_journal_paper_doi               10.1016/j.ica.2019.119240
_journal_volume                  500
_journal_year                    2020
_chemical_formula_moiety         'C32 H54 Cl2 Cu3 N10 O16'
_chemical_formula_sum            'C32 H54 Cl2 Cu3 N10 O16'
_chemical_formula_weight         1096.36
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_cell_angle_alpha                109.4770(10)
_cell_angle_beta                 96.250(2)
_cell_angle_gamma                101.096(2)
_cell_formula_units_Z            1
_cell_length_a                   7.8091(2)
_cell_length_b                   11.1617(3)
_cell_length_c                   13.1597(4)
_cell_measurement_reflns_used    9980
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.00
_cell_measurement_theta_min      3.00
_cell_volume                     1042.46(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXT 2014/4 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       w-scans
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0703
_diffrn_reflns_av_unetI/netI     0.0322
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            61233
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        28.000
_diffrn_reflns_theta_max         28.000
_diffrn_reflns_theta_min         2.902
_exptl_absorpt_coefficient_mu    1.728
_exptl_absorpt_correction_T_max  0.8457
_exptl_absorpt_correction_T_min  0.6732
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.746
_exptl_crystal_description       prism
_exptl_crystal_F_000             565
_exptl_crystal_size_max          0.240
_exptl_crystal_size_mid          0.170
_exptl_crystal_size_min          0.120
_refine_diff_density_max         0.422
_refine_diff_density_min         -0.401
_refine_diff_density_rms         0.066
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.926
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     310
_refine_ls_number_reflns         5031
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.926
_refine_ls_R_factor_all          0.0311
_refine_ls_R_factor_gt           0.0240
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0292P)²+0.9665P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0589
_refine_ls_wR_factor_ref         0.0615
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                4337
_reflns_number_total             5031
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ICA-2020-500-119240.cif
_cod_data_source_block           rf863
_cod_database_code               1565650
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.682
_shelx_estimated_absorpt_t_max   0.819
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.55009(3) 0.43578(2) 0.22067(2) 0.00767(6) Uani 1 1 d . . . . .
H1N H 0.521(3) 0.412(2) 0.4021(18) 0.017(6) Uiso 1 1 d . . . . .
O1 O 0.46624(16) 0.59977(11) 0.25689(10) 0.0131(3) Uani 1 1 d . . . . .
Cl1 Cl 0.12637(5) 1.10280(4) 0.81584(3) 0.01090(9) Uani 1 1 d . . . . .
C1 C 0.8233(2) 0.29537(17) 0.25365(14) 0.0121(3) Uani 1 1 d . . . . .
H1A H 0.910952 0.367453 0.246232 0.014 Uiso 1 1 calc R U . . .
H1B H 0.867766 0.215175 0.227496 0.014 Uiso 1 1 calc R U . . .
N1 N 0.65072(18) 0.27392(13) 0.17932(11) 0.0082(3) Uani 1 1 d . . . . .
C3 C 0.7808(2) 0.46103(18) 0.43213(14) 0.0157(4) Uani 1 1 d . . . . .
H3A H 0.790801 0.478247 0.511640 0.019 Uiso 1 1 calc R U . . .
H3B H 0.871411 0.530048 0.422898 0.019 Uiso 1 1 calc R U . . .
H3N H 0.307(3) 0.313(2) 0.053(2) 0.018(6) Uiso 1 1 d . . . . .
N3 N 0.3088(2) 0.33144(15) 0.12069(13) 0.0117(3) Uani 1 1 d . . . . .
O3 O 0.14687(16) 1.16867(11) 0.51039(10) 0.0119(2) Uani 1 1 d . . . . .
Cu2 Cu 0.000000 1.000000 0.500000 0.00901(7) Uani 1 2 d S . P . .
H2N H 0.587(3) 0.539(3) 0.416(2) 0.029(7) Uiso 1 1 d . . . . .
O2 O 0.18104(18) 0.53860(12) 0.27242(12) 0.0212(3) Uani 1 1 d . . . . .
C2 C 0.8169(2) 0.32823(17) 0.37510(14) 0.0141(4) Uani 1 1 d . . . . .
H2A H 0.723241 0.259763 0.382626 0.017 Uiso 1 1 calc R U . . .
H2B H 0.931787 0.325350 0.413119 0.017 Uiso 1 1 calc R U . . .
N2 N 0.6018(2) 0.46724(16) 0.38729(12) 0.0126(3) Uani 1 1 d . . . . .
C4 C 0.5230(2) 0.16033(16) 0.18844(14) 0.0102(3) Uani 1 1 d . . . . .
H4A H 0.505541 0.184763 0.265454 0.012 Uiso 1 1 calc R U . . .
H4B H 0.579460 0.085567 0.172924 0.012 Uiso 1 1 calc R U . . .
H4N H 0.245(3) 0.386(2) 0.1390(19) 0.021(6) Uiso 1 1 d . . . . .
N4 N 0.7586(2) 0.53773(16) 0.16955(14) 0.0151(3) Uani 1 1 d . . . . .
O4 O 0.38912(17) 1.25198(12) 0.45556(10) 0.0139(3) Uani 1 1 d . . . . .
C5 C 0.3408(2) 0.11335(16) 0.11447(14) 0.0117(3) Uani 1 1 d . . . . .
H5A H 0.356879 0.092068 0.037374 0.014 Uiso 1 1 calc R U . . .
H5B H 0.276718 0.031608 0.121335 0.014 Uiso 1 1 calc R U . . .
H5N H 0.865(3) 0.558(2) 0.210(2) 0.027(6) Uiso 1 1 d . . . . .
N5 N 0.18412(18) 0.92933(13) 0.42990(11) 0.0083(3) Uani 1 1 d . . . . .
O5 O 0.09528(19) 1.01666(14) 0.87556(12) 0.0236(3) Uani 1 1 d . . . . .
C6 C 0.2268(2) 0.21162(17) 0.13966(15) 0.0134(3) Uani 1 1 d . . . . .
H6A H 0.107692 0.171458 0.092436 0.016 Uiso 1 1 calc R U . . .
H6B H 0.211854 0.235111 0.217088 0.016 Uiso 1 1 calc R U . . .
H6N H 0.739(3) 0.611(2) 0.1765(19) 0.023(6) Uiso 1 1 d . . . . .
O6 O -0.0155(2) 1.16722(16) 0.81421(11) 0.0273(3) Uani 1 1 d . . . . .
O7 O 0.29200(17) 1.20173(13) 0.86962(10) 0.0184(3) Uani 1 1 d . . . . .
C7 C 0.6828(2) 0.23766(17) 0.06375(14) 0.0120(3) Uani 1 1 d . . . . .
H7A H 0.567682 0.218299 0.014467 0.014 Uiso 1 1 calc R U . . .
H7B H 0.723845 0.155703 0.044813 0.014 Uiso 1 1 calc R U . . .
O8 O 0.14173(17) 1.02856(13) 0.70519(10) 0.0175(3) Uani 1 1 d . . . . .
C8 C 0.8163(2) 0.33879(18) 0.03909(15) 0.0146(4) Uani 1 1 d . . . . .
H8A H 0.931917 0.357951 0.087768 0.018 Uiso 1 1 calc R U . . .
H8B H 0.833059 0.299384 -0.037424 0.018 Uiso 1 1 calc R U . . .
C9 C 0.7658(3) 0.46766(18) 0.05308(15) 0.0162(4) Uani 1 1 d . . . . .
H9A H 0.854226 0.523238 0.028765 0.019 Uiso 1 1 calc R U . . .
H9B H 0.648369 0.450201 0.006769 0.019 Uiso 1 1 calc R U . . .
C10 C 0.3095(2) 1.02213(15) 0.41721(13) 0.0080(3) Uani 1 1 d . . . . .
C11 C 0.4486(2) 0.99153(16) 0.36558(13) 0.0098(3) Uani 1 1 d . . . . .
H11 H 0.537964 1.058309 0.359357 0.012 Uiso 1 1 calc R U . . .
C12 C 0.4550(2) 0.86059(16) 0.32280(14) 0.0100(3) Uani 1 1 d . . . . .
H12 H 0.549582 0.836880 0.287288 0.012 Uiso 1 1 calc R U . . .
C13 C 0.3219(2) 0.76507(16) 0.33252(13) 0.0090(3) Uani 1 1 d . . . . .
C14 C 0.1885(2) 0.80352(16) 0.38797(13) 0.0088(3) Uani 1 1 d . . . . .
H14 H 0.098277 0.738833 0.396250 0.011 Uiso 1 1 calc R U . . .
C15 C 0.2826(2) 1.16026(16) 0.46444(13) 0.0098(3) Uani 1 1 d . . . . .
C16 C 0.3198(2) 0.62168(16) 0.28378(14) 0.0113(3) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cu1 N1 175.84(5) . .
O1 Cu1 N3 90.23(6) . .
N1 Cu1 N3 91.95(6) . .
O1 Cu1 N2 89.08(6) . .
N1 Cu1 N2 92.72(6) . .
N3 Cu1 N2 122.87(6) . .
O1 Cu1 N4 85.03(6) . .
N1 Cu1 N4 90.81(6) . .
N3 Cu1 N4 123.61(7) . .
N2 Cu1 N4 113.22(7) . .
C16 O1 Cu1 129.89(11) . .
O6 Cl1 O5 110.25(9) . .
O6 Cl1 O8 110.39(8) . .
O5 Cl1 O8 109.47(8) . .
O6 Cl1 O7 108.74(9) . .
O5 Cl1 O7 109.08(8) . .
O8 Cl1 O7 108.88(8) . .
N1 C1 C2 116.24(14) . .
N1 C1 H1A 108.2 . .
C2 C1 H1A 108.2 . .
N1 C1 H1B 108.2 . .
C2 C1 H1B 108.2 . .
H1A C1 H1B 107.4 . .
C7 N1 C4 108.92(12) . .
C7 N1 C1 108.16(13) . .
C4 N1 C1 107.06(12) . .
C7 N1 Cu1 110.24(10) . .
C4 N1 Cu1 110.22(10) . .
C1 N1 Cu1 112.13(10) . .
N2 C3 C2 111.58(14) . .
N2 C3 H3A 109.3 . .
C2 C3 H3A 109.3 . .
N2 C3 H3B 109.3 . .
C2 C3 H3B 109.3 . .
H3A C3 H3B 108.0 . .
C6 N3 Cu1 114.81(11) . .
C6 N3 H3N 109.2(15) . .
Cu1 N3 H3N 115.1(15) . .
C6 N3 H4N 108.5(16) . .
Cu1 N3 H4N 101.9(16) . .
H3N N3 H4N 107(2) . .
C15 O3 Cu2 114.41(10) . .
N5 Cu2 N5 180.0 . 2_576
N5 Cu2 O3 83.97(5) . .
N5 Cu2 O3 96.03(5) 2_576 .
N5 Cu2 O3 96.03(5) . 2_576
N5 Cu2 O3 83.97(5) 2_576 2_576
O3 Cu2 O3 180.0 . 2_576
C3 C2 C1 114.59(14) . .
C3 C2 H2A 108.6 . .
C1 C2 H2A 108.6 . .
C3 C2 H2B 108.6 . .
C1 C2 H2B 108.6 . .
H2A C2 H2B 107.6 . .
C3 N2 Cu1 116.34(11) . .
C3 N2 H1N 109.4(14) . .
Cu1 N2 H1N 109.6(14) . .
C3 N2 H2N 110.6(18) . .
Cu1 N2 H2N 103.2(18) . .
H1N N2 H2N 107(2) . .
N1 C4 C5 117.09(14) . .
N1 C4 H4A 108.0 . .
C5 C4 H4A 108.0 . .
N1 C4 H4B 108.0 . .
C5 C4 H4B 108.0 . .
H4A C4 H4B 107.3 . .
C9 N4 Cu1 111.53(12) . .
C9 N4 H5N 109.5(16) . .
Cu1 N4 H5N 116.3(16) . .
C9 N4 H6N 109.0(16) . .
Cu1 N4 H6N 107.1(16) . .
H5N N4 H6N 103(2) . .
C6 C5 C4 114.29(14) . .
C6 C5 H5A 108.7 . .
C4 C5 H5A 108.7 . .
C6 C5 H5B 108.7 . .
C4 C5 H5B 108.7 . .
H5A C5 H5B 107.6 . .
C14 N5 C10 119.96(14) . .
C14 N5 Cu2 127.25(12) . .
C10 N5 Cu2 112.56(11) . .
N3 C6 C5 110.99(14) . .
N3 C6 H6A 109.4 . .
C5 C6 H6A 109.4 . .
N3 C6 H6B 109.4 . .
C5 C6 H6B 109.4 . .
H6A C6 H6B 108.0 . .
N1 C7 C8 116.85(14) . .
N1 C7 H7A 108.1 . .
C8 C7 H7A 108.1 . .
N1 C7 H7B 108.1 . .
C8 C7 H7B 108.1 . .
H7A C7 H7B 107.3 . .
C9 C8 C7 115.53(14) . .
C9 C8 H8A 108.4 . .
C7 C8 H8A 108.4 . .
C9 C8 H8B 108.4 . .
C7 C8 H8B 108.4 . .
H8A C8 H8B 107.5 . .
N4 C9 C8 110.43(15) . .
N4 C9 H9A 109.6 . .
C8 C9 H9A 109.6 . .
N4 C9 H9B 109.6 . .
C8 C9 H9B 109.6 . .
H9A C9 H9B 108.1 . .
N5 C10 C11 121.70(15) . .
N5 C10 C15 114.10(14) . .
C11 C10 C15 124.20(15) . .
C10 C11 C12 118.56(15) . .
C10 C11 H11 120.7 . .
C12 C11 H11 120.7 . .
C13 C12 C11 119.43(15) . .
C13 C12 H12 120.3 . .
C11 C12 H12 120.3 . .
C12 C13 C14 118.79(15) . .
C12 C13 C16 121.22(15) . .
C14 C13 C16 119.99(15) . .
N5 C14 C13 121.50(15) . .
N5 C14 H14 119.3 . .
C13 C14 H14 119.3 . .
O4 C15 O3 126.18(15) . .
O4 C15 C10 119.04(15) . .
O3 C15 C10 114.77(14) . .
O2 C16 O1 126.86(16) . .
O2 C16 C13 118.94(15) . .
O1 C16 C13 114.19(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 O1 1.9883(12) .
Cu1 N1 2.0400(14) .
Cu1 N3 2.0572(15) .
Cu1 N2 2.0818(15) .
Cu1 N4 2.1059(16) .
O1 C16 1.277(2) .
Cl1 O6 1.4339(14) .
Cl1 O5 1.4340(14) .
Cl1 O8 1.4468(13) .
Cl1 O7 1.4570(13) .
C1 N1 1.505(2) .
C1 C2 1.525(2) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
N1 C7 1.500(2) .
N1 C4 1.502(2) .
C3 N2 1.480(2) .
C3 C2 1.518(2) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
N3 C6 1.479(2) .
N3 H3N 0.84(2) .
N3 H4N 0.84(2) .
O3 C15 1.280(2) .
O3 Cu2 1.9600(12) .
Cu2 N5 1.9444(14) .
Cu2 N5 1.9444(14) 2_576
O2 C16 1.242(2) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
N2 H1N 0.88(2) .
N2 H2N 0.80(3) .
C4 C5 1.522(2) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
N4 C9 1.483(2) .
N4 H5N 0.88(3) .
N4 H6N 0.84(2) .
O4 C15 1.236(2) .
C5 C6 1.518(2) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
N5 C14 1.335(2) .
N5 C10 1.349(2) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.527(2) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.522(2) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.381(2) .
C10 C15 1.524(2) .
C11 C12 1.393(2) .
C11 H11 0.9500 .
C12 C13 1.388(2) .
C12 H12 0.9500 .
C13 C14 1.390(2) .
C13 C16 1.509(2) .
C14 H14 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C2 C1 N1 C7 -177.74(14) . . . .
C2 C1 N1 C4 -60.51(17) . . . .
C2 C1 N1 Cu1 60.50(16) . . . .
N2 C3 C2 C1 64.6(2) . . . .
N1 C1 C2 C3 -67.7(2) . . . .
C2 C3 N2 Cu1 -59.56(17) . . . .
C7 N1 C4 C5 -59.31(18) . . . .
C1 N1 C4 C5 -176.04(14) . . . .
Cu1 N1 C4 C5 61.76(16) . . . .
N1 C4 C5 C6 -66.0(2) . . . .
Cu1 N3 C6 C5 -63.47(17) . . . .
C4 C5 C6 N3 63.65(19) . . . .
C4 N1 C7 C8 -177.34(14) . . . .
C1 N1 C7 C8 -61.31(18) . . . .
Cu1 N1 C7 C8 61.61(16) . . . .
N1 C7 C8 C9 -63.5(2) . . . .
Cu1 N4 C9 C8 -66.64(17) . . . .
C7 C8 C9 N4 64.4(2) . . . .
C14 N5 C10 C11 -2.8(2) . . . .
Cu2 N5 C10 C11 -177.63(13) . . . .
C14 N5 C10 C15 177.18(14) . . . .
Cu2 N5 C10 C15 2.38(17) . . . .
N5 C10 C11 C12 2.0(2) . . . .
C15 C10 C11 C12 -177.97(15) . . . .
C10 C11 C12 C13 0.4(2) . . . .
C11 C12 C13 C14 -2.0(2) . . . .
C11 C12 C13 C16 177.73(15) . . . .
C10 N5 C14 C13 1.1(2) . . . .
Cu2 N5 C14 C13 175.09(12) . . . .
C12 C13 C14 N5 1.3(2) . . . .
C16 C13 C14 N5 -178.45(15) . . . .
Cu2 O3 C15 O4 176.17(14) . . . .
Cu2 O3 C15 C10 -3.68(17) . . . .
N5 C10 C15 O4 -179.00(15) . . . .
C11 C10 C15 O4 1.0(2) . . . .
N5 C10 C15 O3 0.9(2) . . . .
C11 C10 C15 O3 -179.12(15) . . . .
Cu1 O1 C16 O2 -15.6(3) . . . .
Cu1 O1 C16 C13 165.34(11) . . . .
C12 C13 C16 O2 -164.05(17) . . . .
C14 C13 C16 O2 15.7(2) . . . .
C12 C13 C16 O1 15.1(2) . . . .
C14 C13 C16 O1 -165.19(15) . . . .
