Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out
Authors of publication
Zhu, Yun; Stollenz, Michael; Zarcone, Samuel R.; Kharel, Sugam; Joshi, Hemant; Bhuvanesh, Nattamai; Reibenspies, Joseph H.; Gladysz, John A.
Journal of publication
Chemical Science
Year of publication
2022
a
9.0197 ± 0.0005 Å
b
26.5241 ± 0.0015 Å
c
35.839 ± 0.002 Å
α
81.639 ± 0.003°
β
85.64 ± 0.003°
γ
87.03 ± 0.003°
Cell volume
8451.2 ± 0.8 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.1582
Residual factor for significantly intense reflections
0.1249
Weighted residual factors for significantly intense reflections
0.2338
Weighted residual factors for all reflections included in the refinement
0.2478
Goodness-of-fit parameter for all reflections included in the refinement
