Information card for entry 1568813

Structure parameters

• Chemical name: [(NDipp)2(CMe)2(C5H3N)]RhMe
• Formula: C37.25 H51.5 N3 Rh
• Calculated formula: C37.25 H51.5 N3 Rh
• Title of publication: Putting cyaphide in its place: determining the donor/acceptor properties of the κC-cyaphido ligand
• Authors of publication: Yang, Eric S.; Combey, Emma; Goicoechea, Jose M.
• Journal of publication: Chemical Science
• Year of publication: 2023
• Journal volume: 14
• Journal issue: 17
• Pages of publication: 4627 - 4632
• a: 16.0874 ± 0.0011 Å
• b: 16.5041 ± 0.001 Å
• c: 17.143 ± 0.0008 Å
• α: 86.593 ± 0.004°
• β: 64.6 ± 0.005°
• γ: 61.518 ± 0.007°
• Cell volume: 3553.1 ± 0.5 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0742
• Residual factor for significantly intense reflections: 0.0574
• Weighted residual factors for significantly intense reflections: 0.149
• Weighted residual factors for all reflections included in the refinement: 0.1693
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No