Information card for entry 1570318

Structure parameters

• Formula: C56 H52 Cl2 Ge O2 P2
• Calculated formula: C56 H52 Cl2 Ge O2 P2
• SMILES: [Ge](c1ccc2c3c(ccc(P(c4ccccc4)c4ccccc4)c13)CC2)(Cl)(Cl)c1ccc2c3c(ccc(P(c4ccccc4)c4ccccc4)c13)CC2.C1CCCO1.C1OCCC1
• Title of publication: Intramolecular donor-stabilized tetra-coordinated germanium(iv) di-cations and their Lewis acidic properties.
• Authors of publication: Peddi, Balakrishna; Khan, Souvik; Gonnade, Rajesh G.; Yildiz, Cem B.; Majumdar, Moumita
• Journal of publication: Chemical science
• Year of publication: 2023
• Journal volume: 14
• Journal issue: 47
• Pages of publication: 13755 - 13764
• a: 22.1656 ± 0.0019 Å
• b: 10.1752 ± 0.0009 Å
• c: 20.7492 ± 0.0017 Å
• α: 90°
• β: 102.393 ± 0.003°
• γ: 90°
• Cell volume: 4570.7 ± 0.7 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0413
• Residual factor for significantly intense reflections: 0.0379
• Weighted residual factors for significantly intense reflections: 0.0978
• Weighted residual factors for all reflections included in the refinement: 0.1007
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No