Information card for entry 1570713

Structure parameters

• Formula: C10 H8 Cl4 N8 Si
• Calculated formula: C10 H8 Cl4 N8 Si
• SMILES: Cl[Si]([n]1ccc(cc1)N=N#N)([n]1ccc(cc1)N=N#N)(Cl)(Cl)Cl
• Title of publication: The Hexacoordinate Si Complex SiCl4(4-Azidopyridine)2—Crystallographic Characterization of Two Conformers and Probing the Influence of SiCl4-Complexation on a Click Reaction with Phenylacetylene
• Authors of publication: Riedel, Sophie; Gerwig, Maik; Gerlach, Daniela; Brendler, Erica; Gericke, Robert; Kroke, Edwin; Wagler, Jörg
• Journal of publication: Inorganics
• Year of publication: 2023
• Journal volume: 11
• Journal issue: 12
• Pages of publication: 473
• a: 7.292 ± 0.0006 Å
• b: 10.7627 ± 0.0006 Å
• c: 10.0442 ± 0.0008 Å
• α: 90°
• β: 94.795 ± 0.006°
• γ: 90°
• Cell volume: 785.53 ± 0.1 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0386
• Residual factor for significantly intense reflections: 0.032
• Weighted residual factors for significantly intense reflections: 0.072
• Weighted residual factors for all reflections included in the refinement: 0.077
• Goodness-of-fit parameter for all reflections included in the refinement: 1.277
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No