Information card for entry 1572017

Structure parameters

• Formula: C14 H20 F10 P S2 Sb
• Calculated formula: C14 H20 F10 P S2 Sb
• SMILES: [Sb](C(F)(F)C(F)(F)F)(C(F)(F)C(F)(F)F)C[P+](C(C)(C)C)(C(C)(C)C)C(=S)[S-]
• Title of publication: A geminal antimony(iii)/phosphorus(iii) frustrated Lewis pair.
• Authors of publication: Krieft, Jonas; Trapp, Pia C.; Vishnevskiy, Yury V.; Neumann, Beate; Stammler, Hans-Georg; Lamm, Jan-Hendrik; Mitzel, Norbert W.
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 15
• Journal issue: 30
• Pages of publication: 12118 - 12125
• a: 8.6271 ± 0.0006 Å
• b: 11.2928 ± 0.0009 Å
• c: 12.0061 ± 0.001 Å
• α: 74.243 ± 0.007°
• β: 74.812 ± 0.007°
• γ: 70.602 ± 0.007°
• Cell volume: 1042.64 ± 0.15 ų
• Cell temperature: 100.01 ± 0.1 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0315
• Residual factor for significantly intense reflections: 0.0292
• Weighted residual factors for significantly intense reflections: 0.0696
• Weighted residual factors for all reflections included in the refinement: 0.0723
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No