Information card for entry 1573279

Structure parameters

• Formula: C18 H49 N2 Si3 Sm
• Calculated formula: C18 H49 N2 Si3 Sm
• SMILES: [Sm]1([N](C)(C)CC[N]1(C)C)(C[Si](C)(C)C)(C[Si](C)(C)C)C[Si](C)(C)C
• Title of publication: Stabilization of reactive rare earth alkyl complexes through mechanistic studies.
• Authors of publication: Tanuhadi, Elias; Bair, Anna S.; Johnson, Mary; Fontaine, Philip; Klosin, Jerzy; Pal, Sudipta; Arnold, Polly L.
• Journal of publication: Chemical science
• Year of publication: 2024
• Journal volume: 16
• Journal issue: 1
• Pages of publication: 280 - 287
• a: 9.8737 ± 0.0001 Å
• b: 16.2253 ± 0.0001 Å
• c: 17.3545 ± 0.0001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2780.26 ± 0.04 ų
• Cell temperature: 99.9 ± 0.4 K
• Ambient diffraction temperature: 99.9 ± 0.4 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0313
• Residual factor for significantly intense reflections: 0.0311
• Weighted residual factors for significantly intense reflections: 0.0855
• Weighted residual factors for all reflections included in the refinement: 0.0856
• Goodness-of-fit parameter for all reflections included in the refinement: 1.111
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No