Information card for entry 1573993

Structure parameters

• Formula: C41.5 H37 Cl5 Co F3 I2 N2 P3
• Calculated formula: C41.5 H37 Cl5 Co F3 I2 N2 P3
• Title of publication: Efficient and selective hydroboration of alkenes catalyzed by an air-stable (PP^CF3P)CoI₂ precatalyst.
• Authors of publication: Fitzsimmons, Matthew C.; Seith, Maria C.; Moore, Curtis E.; Thomas, Christine M.
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 13
• Pages of publication: 5717 - 5725
• a: 12.5715 ± 0.0006 Å
• b: 13.3397 ± 0.0006 Å
• c: 15.6881 ± 0.0008 Å
• α: 87.496 ± 0.002°
• β: 73.663 ± 0.002°
• γ: 62.081 ± 0.001°
• Cell volume: 2218.77 ± 0.19 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0321
• Residual factor for significantly intense reflections: 0.0241
• Weighted residual factors for significantly intense reflections: 0.0518
• Weighted residual factors for all reflections included in the refinement: 0.0553
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Diffraction radiation X-ray symbol: K-L~3~
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No