Information card for entry 1574073

Structure parameters

• Formula: C32 H56 B10 Ga I2 N4 Si2
• Calculated formula: C32 H56 B10 Ga I2 N4 Si2
• SMILES: [BH]1234[C]567[Si]8([N](=C(c9ccccc9)N8C(C)(C)C)C(C)(C)C)[Ga](I)(I)[Si]8([C]9%103[BH]3%115[BH]5%129[BH]9%13%14[BH]%15%16%17[BH]16([BH]2%13%16[BH]4%10%12%14)[BH]7%11%17[BH]359%15)[N](=C(c1ccccc1)N8C(C)(C)C)C(C)(C)C
• Title of publication: Redox non-innocent bis-silylene aluminium complexes with a carborane backbone
• Authors of publication: Saddington, Artemis; Yao, Shenglai; Lorent, Christian; Driess, Matthias
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 15
• Pages of publication: 6383 - 6391
• a: 23.2436 ± 0.0003 Å
• b: 18.9817 ± 0.0003 Å
• c: 13.9956 ± 0.0002 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6174.9 ± 0.15 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 63
• Hermann-Mauguin space group symbol: C m c m
• Hall space group symbol: -C 2c 2
• Residual factor for all reflections: 0.0418
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for significantly intense reflections: 0.1049
• Weighted residual factors for all reflections included in the refinement: 0.1084
• Goodness-of-fit parameter for all reflections included in the refinement: 1.065
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No