Information card for entry 1574609

Structure parameters

• Formula: C32 H23 B Cl P S
• Calculated formula: C32 H23 B Cl P S
• Title of publication: Borinine-FLP ring expansion: isolation of eight-membered B–P rings bridged by μ2 chalcogenide and chloronium ions
• Authors of publication: Frey, Nathan C.; Sarkar, Samir Kumar; Dickie, Diane A.; Molino, Andrew; Gilliard, Robert J.
• Journal of publication: Chemical Science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 24
• Pages of publication: 10857 - 10866
• a: 10.5356 ± 0.0004 Å
• b: 10.8441 ± 0.0004 Å
• c: 11.7844 ± 0.0005 Å
• α: 92.322 ± 0.003°
• β: 97.327 ± 0.003°
• γ: 107.799 ± 0.003°
• Cell volume: 1266.93 ± 0.09 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.071
• Residual factor for significantly intense reflections: 0.0505
• Weighted residual factors for significantly intense reflections: 0.1252
• Weighted residual factors for all reflections included in the refinement: 0.1379
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No