Information card for entry 1575463

Structure parameters

• Formula: C84 H85 Au2 D24 N5 Si2
• Calculated formula: C84 H85 Au2 D24 N5 Si2
• Title of publication: On-demand switching from mono-silylene to bis-silylene to access mono-, di- and mixed coinage metal complexes.
• Authors of publication: Sun, Xiaofei; Jin, Da; Yadav, Ravi; Kraetschmer, Frederic; Köppe, Ralf; Roesky, Peter W.
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 35
• Pages of publication: 16057 - 16062
• a: 23.4582 ± 0.0017 Å
• b: 13.7319 ± 0.0008 Å
• c: 25.714 ± 0.0019 Å
• α: 90°
• β: 113.237 ± 0.005°
• γ: 90°
• Cell volume: 7611.2 ± 0.9 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0495
• Residual factor for significantly intense reflections: 0.0365
• Weighted residual factors for significantly intense reflections: 0.0941
• Weighted residual factors for all reflections included in the refinement: 0.0989
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No