Information card for entry 1575465

Structure parameters

• Formula: C60 H74 Au D9 N5 Si2
• Calculated formula: C60 H74 Au D9 N5 Si2
• Title of publication: On-demand switching from mono-silylene to bis-silylene to access mono-, di- and mixed coinage metal complexes.
• Authors of publication: Sun, Xiaofei; Jin, Da; Yadav, Ravi; Kraetschmer, Frederic; Köppe, Ralf; Roesky, Peter W.
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 35
• Pages of publication: 16057 - 16062
• a: 12.4819 ± 0.0019 Å
• b: 15.9578 ± 0.0012 Å
• c: 16.797 ± 0.0014 Å
• α: 71.514 ± 0.006°
• β: 69.239 ± 0.01°
• γ: 70.868 ± 0.01°
• Cell volume: 2878.2 ± 0.6 ų
• Cell temperature: 110 K
• Ambient diffraction temperature: 110 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0353
• Residual factor for significantly intense reflections: 0.0294
• Weighted residual factors for significantly intense reflections: 0.0713
• Weighted residual factors for all reflections included in the refinement: 0.0736
• Goodness-of-fit parameter for all reflections included in the refinement: 1.038
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No