Information card for entry 1575625

Structure parameters

• Chemical name: complex of gold(I) chloride with 4,4',6,6'-Tetrakis(diphenylphosphino)- 2,2'-bis(1,3,5-triazine)
• Formula: C62 H60 Au4 Cl4 N6 O2 P4
• Calculated formula: C58 H50 Au4 Cl4 N6 O P4
• Title of publication: A tetraphosphino-bis(<i>s</i>-triazine) from cyanuric chloride and Ph₂PH: new unexpected tandem C-C/C-P coupling reaction.
• Authors of publication: Artem'ev, Alexander V.; Davydova, Maria P.; Kuzmin, Anton V.; Rakhmanova, Mariana I.; Bagryanskaya, Irina Yu
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2025
• Journal volume: 54
• Journal issue: 38
• Pages of publication: 14440 - 14447
• a: 17.6368 ± 0.001 Å
• b: 21.8612 ± 0.001 Å
• c: 18.3488 ± 0.0009 Å
• α: 90°
• β: 92.894 ± 0.003°
• γ: 90°
• Cell volume: 7065.6 ± 0.6 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 299 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1161
• Residual factor for significantly intense reflections: 0.0539
• Weighted residual factors for significantly intense reflections: 0.112
• Weighted residual factors for all reflections included in the refinement: 0.1404
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No