Information card for entry 1575732

Structure parameters

• Chemical name: Au10(DPPF)4PPh3
• Formula: C162 H143 Au10 Cl17 Fe4 P9
• Calculated formula: C155 H129 Au10 Cl3 Fe4 P9
• Title of publication: An atomically precise Au₁₀(DPPF)₄PPh₃ cluster catalyst for N-hydroformylation of amines.
• Authors of publication: Li, Guangjun; Li, Guoao; Liang, Xinyi; Tian, Yiqi; Lu, Jinzhi; Xu, Xinyi; Liu, Xu; Ma, Jing; Li, Shuhua; Zhu, Yan
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 40
• Pages of publication: 18642 - 18651
• a: 16.8219 ± 0.0015 Å
• b: 31.443 ± 0.003 Å
• c: 33.812 ± 0.003 Å
• α: 90°
• β: 98.172 ± 0.002°
• γ: 90°
• Cell volume: 17703 ± 3 ų
• Cell temperature: 193 K
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0963
• Residual factor for significantly intense reflections: 0.0621
• Weighted residual factors for significantly intense reflections: 0.1354
• Weighted residual factors for all reflections included in the refinement: 0.1526
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No