#------------------------------------------------------------------------------
#$Date: 2025-11-29 21:44:20 +0100 (Sat 29 de Nov de 2025) $
#$Revision: 303773 $
#$URL: svn://www.crystallography.net/cod/cif/1/57/57/1575770.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1575770
loop_
_publ_author_name
'Glok, Eduard'
'Werner, Luis'
'Radius, Udo'
_publ_section_title
;
 N-Heterocyclic silylene complexes of nickel(0).
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14846
_journal_page_last               14861
_journal_paper_doi               10.1039/d5dt01887k
_journal_volume                  54
_journal_year                    2025
_chemical_formula_moiety         'C52 H78 N4 Ni P2 Si2'
_chemical_formula_sum            'C52 H78 N4 Ni P2 Si2'
_chemical_formula_weight         936.01
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2025-08-07 deposited with the CCDC.	2025-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                77.3170(10)
_cell_angle_beta                 89.3230(10)
_cell_angle_gamma                77.7770(10)
_cell_formula_units_Z            2
_cell_length_a                   11.45970(10)
_cell_length_b                   15.07620(10)
_cell_length_c                   15.4869(2)
_cell_measurement_reflns_used    37749
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      74.7550
_cell_measurement_theta_min      2.9210
_cell_volume                     2549.50(5)
_computing_cell_refinement       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_collection       'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_data_reduction        'CrysAlisPro 1.171.40.53 (Rigaku OD, 2019)'
_computing_molecular_graphics    'ShelXLe (Huebschle et all, 2011)'
_computing_publication_material  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'XtaLAB Synergy, Dualflex, HyPix'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0207
_diffrn_reflns_av_unetI/netI     0.0161
_diffrn_reflns_Laue_measured_fraction_full 0.989
_diffrn_reflns_Laue_measured_fraction_max 0.976
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            52813
_diffrn_reflns_point_group_measured_fraction_full 0.989
_diffrn_reflns_point_group_measured_fraction_max 0.976
_diffrn_reflns_theta_full        72.000
_diffrn_reflns_theta_max         75.265
_diffrn_reflns_theta_min         2.927
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    1.873
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.604
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.41.73a (Rigaku Oxford Diffraction, 2020)
Numerical absorption correction based on gaussian integration over
a multifaceted crystal model
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.219
_exptl_crystal_description       block
_exptl_crystal_F_000             1008
_exptl_crystal_size_max          0.230
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.090
_refine_diff_density_max         0.275
_refine_diff_density_min         -0.314
_refine_diff_density_rms         0.046
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     568
_refine_ls_number_reflns         10297
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0289
_refine_ls_R_factor_gt           0.0274
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0347P)²+1.3190P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0723
_refine_ls_wR_factor_ref         0.0731
_reflns_Friedel_coverage         0.000
_reflns_number_gt                9705
_reflns_number_total             10297
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt01887k2.cif
_cod_data_source_block           compound_3
_cod_depositor_comments
'Adding full bibliography for 1575761--1575772.cif.'
_cod_database_code               1575770
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.673
_shelx_estimated_absorpt_t_max   0.850
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ni01 Ni 0.30911(2) 0.69185(2) 0.72758(2) 0.01263(6) Uani 1 1 d . . . . .
Si1 Si 0.30639(3) 0.81824(2) 0.62962(2) 0.01308(7) Uani 1 1 d . . . . .
P002 P 0.45536(3) 0.58130(2) 0.70193(2) 0.01424(7) Uani 1 1 d . . . . .
Si2 Si 0.13341(3) 0.66457(2) 0.72191(2) 0.01342(7) Uani 1 1 d . . . . .
P003 P 0.35062(3) 0.70815(2) 0.86101(2) 0.01378(7) Uani 1 1 d . . . . .
N006 N 0.26403(10) 0.87007(7) 0.51654(7) 0.0163(2) Uani 1 1 d . . . . .
N007 N 0.35253(9) 0.92188(7) 0.63333(7) 0.0158(2) Uani 1 1 d . . . . .
N008 N 0.06218(9) 0.59154(7) 0.67599(7) 0.0171(2) Uani 1 1 d . . . . .
N009 N -0.01042(9) 0.71556(7) 0.75363(7) 0.0170(2) Uani 1 1 d . . . . .
C00A C 0.10104(11) 0.83444(8) 0.43649(8) 0.0158(2) Uani 1 1 d . . . . .
C00B C 0.11522(11) 0.50810(9) 0.64714(9) 0.0168(2) Uani 1 1 d . . . . .
C00C C 0.41419(11) 0.94505(8) 0.70230(8) 0.0157(2) Uani 1 1 d . . . . .
C00D C 0.22211(11) 0.83589(8) 0.44547(8) 0.0156(2) Uani 1 1 d . . . . .
C00E C 0.33483(12) 0.98847(9) 0.55350(9) 0.0196(3) Uani 1 1 d . . . . .
H00E H 0.355066 1.047591 0.545727 0.024 Uiso 1 1 calc R U . . .
C00F C 0.35097(12) 1.00133(9) 0.75539(8) 0.0181(3) Uani 1 1 d . . . . .
C00G C 0.28638(12) 0.95993(9) 0.48935(9) 0.0200(3) Uani 1 1 d . . . . .
H00G H 0.268750 0.996809 0.431004 0.024 Uiso 1 1 calc R U . . .
C00H C 0.19310(11) 0.42903(9) 0.53337(9) 0.0189(3) Uani 1 1 d . . . . .
H00H H 0.214433 0.431387 0.473571 0.023 Uiso 1 1 calc R U . . .
C00I C -0.04507(11) 0.86576(9) 0.79919(8) 0.0164(2) Uani 1 1 d . . . . .
C00J C 0.13354(12) 0.42256(9) 0.70879(9) 0.0184(3) Uani 1 1 d . . . . .
C00K C 0.06242(11) 0.80732(9) 0.36330(8) 0.0171(2) Uani 1 1 d . . . . .
H00K H -0.019523 0.805858 0.357320 0.021 Uiso 1 1 calc R U . . .
C00L C 0.24117(12) 0.79175(9) 0.90756(8) 0.0192(3) Uani 1 1 d . . . . .
H00A H 0.229676 0.853054 0.865630 0.023 Uiso 1 1 calc R U . . .
H00B H 0.163894 0.772034 0.909678 0.023 Uiso 1 1 calc R U . . .
C00M C -0.03890(11) 0.76950(9) 0.81992(8) 0.0167(2) Uani 1 1 d . . . . .
C00N C -0.06881(11) 0.91500(9) 0.86619(9) 0.0190(3) Uani 1 1 d . . . . .
H00N H -0.071847 0.980059 0.852443 0.023 Uiso 1 1 calc R U . . .
C00O C 0.30190(11) 0.81304(9) 0.38013(8) 0.0183(3) Uani 1 1 d . . . . .
C00P C 0.43457(12) 0.46085(9) 0.71546(8) 0.0182(2) Uani 1 1 d . . . . .
H00C H 0.365881 0.461137 0.677149 0.022 Uiso 1 1 calc R U . . .
H00D H 0.506581 0.422732 0.695330 0.022 Uiso 1 1 calc R U . . .
C00Q C 0.21226(11) 0.34321(9) 0.59260(9) 0.0190(3) Uani 1 1 d . . . . .
C00R C 0.21709(12) 1.03500(10) 0.74407(9) 0.0224(3) Uani 1 1 d . . . . .
H00F H 0.194268 1.053051 0.680835 0.034 Uiso 1 1 calc R U . . .
H00I H 0.192042 1.088830 0.770905 0.034 Uiso 1 1 calc R U . . .
H00J H 0.178070 0.984968 0.773125 0.034 Uiso 1 1 calc R U . . .
C00S C 0.36702(12) 0.60265(9) 0.95179(8) 0.0177(2) Uani 1 1 d . . . . .
H00L H 0.426200 0.551592 0.935198 0.021 Uiso 1 1 calc R U . . .
H00M H 0.398642 0.615679 1.005840 0.021 Uiso 1 1 calc R U . . .
C00T C -0.08815(12) 0.87160(10) 0.95249(9) 0.0220(3) Uani 1 1 d . . . . .
C00U C -0.06258(12) 0.72448(9) 0.90584(9) 0.0207(3) Uani 1 1 d . . . . .
C00V C 0.14361(11) 0.51192(9) 0.55863(9) 0.0175(2) Uani 1 1 d . . . . .
C00W C 0.13978(12) 0.78233(9) 0.29876(8) 0.0192(3) Uani 1 1 d . . . . .
C00X C 0.18220(12) 0.34128(9) 0.68025(9) 0.0197(3) Uani 1 1 d . . . . .
H00X H 0.195132 0.283161 0.721732 0.024 Uiso 1 1 calc R U . . .
C00Y C 0.53934(12) 0.91664(9) 0.71093(8) 0.0178(2) Uani 1 1 d . . . . .
C00Z C 0.60613(12) 0.85630(9) 0.65294(9) 0.0220(3) Uani 1 1 d . . . . .
H00O H 0.581463 0.884141 0.590819 0.033 Uiso 1 1 calc R U . . .
H00P H 0.588230 0.794152 0.669426 0.033 Uiso 1 1 calc R U . . .
H00Q H 0.692177 0.851350 0.660823 0.033 Uiso 1 1 calc R U . . .
C010 C 0.01321(12) 0.86157(10) 0.50383(9) 0.0206(3) Uani 1 1 d . . . . .
H01A H -0.067478 0.881275 0.476485 0.031 Uiso 1 1 calc R U . . .
H01B H 0.033685 0.913015 0.525379 0.031 Uiso 1 1 calc R U . . .
H01C H 0.016134 0.808127 0.553574 0.031 Uiso 1 1 calc R U . . .
C011 C 0.59690(11) 0.56180(9) 0.76778(9) 0.0202(3) Uani 1 1 d . . . . .
H01D H 0.630558 0.618085 0.749313 0.024 Uiso 1 1 calc R U . . .
H01E H 0.576368 0.556986 0.830677 0.024 Uiso 1 1 calc R U . . .
C012 C 0.25018(13) 0.57038(10) 0.97274(9) 0.0235(3) Uani 1 1 d . . . . .
H01F H 0.215237 0.561620 0.918580 0.035 Uiso 1 1 calc R U . . .
H01G H 0.194270 0.617451 0.996153 0.035 Uiso 1 1 calc R U . . .
H01H H 0.266020 0.511364 1.016951 0.035 Uiso 1 1 calc R U . . .
C013 C 0.25917(12) 0.78600(9) 0.30837(8) 0.0201(3) Uani 1 1 d . . . . .
H013 H 0.313147 0.769548 0.264602 0.024 Uiso 1 1 calc R U . . .
C014 C 0.51541(12) 0.59829(9) 0.59010(8) 0.0190(3) Uani 1 1 d . . . . .
H01I H 0.546122 0.656288 0.577603 0.023 Uiso 1 1 calc R U . . .
H01J H 0.583302 0.545895 0.588118 0.023 Uiso 1 1 calc R U . . .
C015 C 0.59927(12) 0.94445(10) 0.77434(9) 0.0219(3) Uani 1 1 d . . . . .
H015 H 0.683769 0.925165 0.780801 0.026 Uiso 1 1 calc R U . . .
C016 C 0.49112(12) 0.74830(9) 0.87374(8) 0.0187(3) Uani 1 1 d . . . . .
H01K H 0.542102 0.734441 0.824263 0.022 Uiso 1 1 calc R U . . .
H01L H 0.469427 0.816915 0.864841 0.022 Uiso 1 1 calc R U . . .
C017 C -0.08602(13) 0.77658(10) 0.97039(9) 0.0240(3) Uani 1 1 d . . . . .
H017 H -0.101103 0.746270 1.028691 0.029 Uiso 1 1 calc R U . . .
C018 C -0.06202(12) 0.60999(10) 0.68385(9) 0.0222(3) Uani 1 1 d . . . . .
H018 H -0.112799 0.577662 0.660971 0.027 Uiso 1 1 calc R U . . .
C019 C 0.25815(13) 0.25458(10) 0.56126(10) 0.0247(3) Uani 1 1 d . . . . .
H01M H 0.191977 0.237238 0.534087 0.037 Uiso 1 1 calc R U . . .
H01N H 0.292932 0.204602 0.611806 0.037 Uiso 1 1 calc R U . . .
H01O H 0.319352 0.264347 0.517561 0.037 Uiso 1 1 calc R U . . .
C01A C -0.02886(12) 0.91589(9) 0.70611(9) 0.0199(3) Uani 1 1 d . . . . .
H01P H -0.082503 0.900672 0.665399 0.030 Uiso 1 1 calc R U . . .
H01Q H 0.054095 0.896501 0.689970 0.030 Uiso 1 1 calc R U . . .
H01R H -0.047595 0.983182 0.702254 0.030 Uiso 1 1 calc R U . . .
C01B C -0.10191(12) 0.67771(10) 0.72682(10) 0.0222(3) Uani 1 1 d . . . . .
H01S H -0.183795 0.698073 0.738018 0.027 Uiso 1 1 calc R U . . .
C01C C 0.43180(12) 0.81747(10) 0.38654(9) 0.0234(3) Uani 1 1 d . . . . .
H01T H 0.479028 0.776346 0.351993 0.035 Uiso 1 1 calc R U . . .
H01U H 0.460149 0.797425 0.448658 0.035 Uiso 1 1 calc R U . . .
H01V H 0.440555 0.881525 0.363144 0.035 Uiso 1 1 calc R U . . .
C01D C 0.53858(13) 0.99987(10) 0.82866(9) 0.0253(3) Uani 1 1 d . . . . .
C01E C 0.41464(13) 1.02730(10) 0.81846(9) 0.0229(3) Uani 1 1 d . . . . .
H01W H 0.372313 1.064737 0.855499 0.027 Uiso 1 1 calc R U . . .
C01F C 0.69587(12) 0.47730(10) 0.76288(10) 0.0259(3) Uani 1 1 d . . . . .
H01X H 0.715118 0.478506 0.700866 0.039 Uiso 1 1 calc R U . . .
H01Y H 0.668617 0.420089 0.788577 0.039 Uiso 1 1 calc R U . . .
H01Z H 0.767248 0.479227 0.796061 0.039 Uiso 1 1 calc R U . . .
C01G C 0.42220(13) 0.60424(10) 0.51859(9) 0.0223(3) Uani 1 1 d . . . . .
H010 H 0.458070 0.614176 0.460445 0.033 Uiso 1 1 calc R U . . .
H011 H 0.354987 0.656292 0.519936 0.033 Uiso 1 1 calc R U . . .
H012 H 0.393576 0.546089 0.529381 0.033 Uiso 1 1 calc R U . . .
C01H C -0.06416(14) 0.62219(10) 0.92966(10) 0.0277(3) Uani 1 1 d . . . . .
H014 H -0.142198 0.613287 0.912490 0.042 Uiso 1 1 calc R U . . .
H016 H -0.049818 0.598683 0.993671 0.042 Uiso 1 1 calc R U . . .
H019 H -0.001508 0.588148 0.898271 0.042 Uiso 1 1 calc R U . . .
C01I C 0.26882(14) 0.80559(11) 0.99924(10) 0.0288(3) Uani 1 1 d . . . . .
H020 H 0.338781 0.833716 0.996885 0.043 Uiso 1 1 calc R U . . .
H021 H 0.285440 0.745227 1.041473 0.043 Uiso 1 1 calc R U . . .
H022 H 0.200003 0.846707 1.018238 0.043 Uiso 1 1 calc R U . . .
C01J C 0.10069(14) 0.41749(10) 0.80394(9) 0.0250(3) Uani 1 1 d . . . . .
H023 H 0.135931 0.461448 0.827619 0.037 Uiso 1 1 calc R U . . .
H024 H 0.131211 0.354207 0.838749 0.037 Uiso 1 1 calc R U . . .
H025 H 0.013561 0.433504 0.807359 0.037 Uiso 1 1 calc R U . . .
C01K C 0.11778(13) 0.60269(10) 0.49120(9) 0.0235(3) Uani 1 1 d . . . . .
H026 H 0.156070 0.593989 0.435861 0.035 Uiso 1 1 calc R U . . .
H027 H 0.149176 0.649313 0.513574 0.035 Uiso 1 1 calc R U . . .
H028 H 0.031256 0.623966 0.480203 0.035 Uiso 1 1 calc R U . . .
C01L C 0.09512(13) 0.75023(11) 0.22231(9) 0.0275(3) Uani 1 1 d . . . . .
H029 H 0.013007 0.784354 0.205407 0.041 Uiso 1 1 calc R U . . .
H02A H 0.096874 0.683414 0.239942 0.041 Uiso 1 1 calc R U . . .
H02B H 0.146423 0.762026 0.171851 0.041 Uiso 1 1 calc R U . . .
C01M C -0.11134(14) 0.92455(11) 1.02533(10) 0.0297(3) Uani 1 1 d . . . . .
H02C H -0.143897 0.990506 0.999398 0.045 Uiso 1 1 calc R U . . .
H02D H -0.036329 0.918062 1.058185 0.045 Uiso 1 1 calc R U . . .
H02E H -0.168863 0.899443 1.065686 0.045 Uiso 1 1 calc R U . . .
C01N C 0.41260(13) 0.41580(10) 0.81094(9) 0.0243(3) Uani 1 1 d . . . . .
H02F H 0.346009 0.456101 0.833240 0.036 Uiso 1 1 calc R U . . .
H02G H 0.484734 0.407197 0.847864 0.036 Uiso 1 1 calc R U . . .
H02H H 0.392962 0.355211 0.812955 0.036 Uiso 1 1 calc R U . . .
C01O C 0.56900(13) 0.71125(11) 0.95883(10) 0.0279(3) Uani 1 1 d . . . . .
H02I H 0.594796 0.643438 0.968680 0.042 Uiso 1 1 calc R U . . .
H02J H 0.522855 0.727302 1.008992 0.042 Uiso 1 1 calc R U . . .
H02K H 0.639260 0.739258 0.953345 0.042 Uiso 1 1 calc R U . . .
C01P C 0.60520(16) 1.03059(14) 0.89608(12) 0.0408(4) Uani 1 1 d . . . . .
H02L H 0.669060 1.059105 0.867303 0.061 Uiso 1 1 calc R U . . .
H02M H 0.639960 0.976551 0.943026 0.061 Uiso 1 1 calc R U . . .
H02N H 0.549915 1.076104 0.921773 0.061 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni -3.0029 0.5091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si2 Ni01 Si1 105.837(15) . . ?
Si2 Ni01 P002 115.268(15) . . ?
Si1 Ni01 P002 109.472(15) . . ?
Si2 Ni01 P003 110.150(15) . . ?
Si1 Ni01 P003 111.222(15) . . ?
P002 Ni01 P003 104.985(14) . . ?
N007 Si1 N006 86.57(5) . . ?
N007 Si1 Ni01 132.55(4) . . ?
N006 Si1 Ni01 140.88(4) . . ?
C014 P002 C00P 99.49(6) . . ?
C014 P002 C011 99.00(6) . . ?
C00P P002 C011 101.18(6) . . ?
C014 P002 Ni01 116.97(4) . . ?
C00P P002 Ni01 120.64(4) . . ?
C011 P002 Ni01 115.96(4) . . ?
N008 Si2 N009 86.87(5) . . ?
N008 Si2 Ni01 137.68(4) . . ?
N009 Si2 Ni01 135.21(4) . . ?
C00L P003 C00S 100.74(6) . . ?
C00L P003 C016 101.51(6) . . ?
C00S P003 C016 102.64(6) . . ?
C00L P003 Ni01 117.11(4) . . ?
C00S P003 Ni01 116.45(4) . . ?
C016 P003 Ni01 115.90(4) . . ?
C00G N006 C00D 113.42(10) . . ?
C00G N006 Si1 113.04(8) . . ?
C00D N006 Si1 133.25(8) . . ?
C00E N007 C00C 115.16(10) . . ?
C00E N007 Si1 114.34(8) . . ?
C00C N007 Si1 130.24(8) . . ?
C018 N008 C00B 116.77(10) . . ?
C018 N008 Si2 113.60(9) . . ?
C00B N008 Si2 128.61(8) . . ?
C01B N009 C00M 116.62(11) . . ?
C01B N009 Si2 113.27(9) . . ?
C00M N009 Si2 127.88(8) . . ?
C00K C00A C00D 118.79(11) . . ?
C00K C00A C010 119.89(11) . . ?
C00D C00A C010 121.32(11) . . ?
C00V C00B C00J 120.70(12) . . ?
C00V C00B N008 120.51(11) . . ?
C00J C00B N008 118.74(11) . . ?
C00F C00C C00Y 120.90(12) . . ?
C00F C00C N007 119.85(11) . . ?
C00Y C00C N007 119.06(11) . . ?
C00A C00D C00O 120.27(11) . . ?
C00A C00D N006 120.50(11) . . ?
C00O C00D N006 118.91(11) . . ?
C00G C00E N007 112.63(11) . . ?
C00G C00E H00E 123.7 . . ?
N007 C00E H00E 123.7 . . ?
C01E C00F C00C 118.47(12) . . ?
C01E C00F C00R 120.41(12) . . ?
C00C C00F C00R 121.11(11) . . ?
C00E C00G N006 113.42(11) . . ?
C00E C00G H00G 123.3 . . ?
N006 C00G H00G 123.3 . . ?
C00Q C00H C00V 122.27(12) . . ?
C00Q C00H H00H 118.9 . . ?
C00V C00H H00H 118.9 . . ?
C00N C00I C00M 118.94(12) . . ?
C00N C00I C01A 120.22(11) . . ?
C00M C00I C01A 120.83(11) . . ?
C00X C00J C00B 118.74(12) . . ?
C00X C00J C01J 120.14(12) . . ?
C00B C00J C01J 121.12(12) . . ?
C00W C00K C00A 122.16(12) . . ?
C00W C00K H00K 118.9 . . ?
C00A C00K H00K 118.9 . . ?
C01I C00L P003 118.15(10) . . ?
C01I C00L H00A 107.8 . . ?
P003 C00L H00A 107.8 . . ?
C01I C00L H00B 107.8 . . ?
P003 C00L H00B 107.8 . . ?
H00A C00L H00B 107.1 . . ?
C00I C00M C00U 120.28(12) . . ?
C00I C00M N009 120.76(11) . . ?
C00U C00M N009 118.95(11) . . ?
C00T C00N C00I 121.91(12) . . ?
C00T C00N H00N 119.0 . . ?
C00I C00N H00N 119.0 . . ?
C013 C00O C00D 118.80(12) . . ?
C013 C00O C01C 119.90(12) . . ?
C00D C00O C01C 121.31(12) . . ?
C01N C00P P002 113.12(9) . . ?
C01N C00P H00C 109.0 . . ?
P002 C00P H00C 109.0 . . ?
C01N C00P H00D 109.0 . . ?
P002 C00P H00D 109.0 . . ?
H00C C00P H00D 107.8 . . ?
C00H C00Q C00X 118.04(12) . . ?
C00H C00Q C019 120.59(12) . . ?
C00X C00Q C019 121.29(12) . . ?
C00F C00R H00F 109.5 . . ?
C00F C00R H00I 109.5 . . ?
H00F C00R H00I 109.5 . . ?
C00F C00R H00J 109.5 . . ?
H00F C00R H00J 109.5 . . ?
H00I C00R H00J 109.5 . . ?
C012 C00S P003 113.41(9) . . ?
C012 C00S H00L 108.9 . . ?
P003 C00S H00L 108.9 . . ?
C012 C00S H00M 108.9 . . ?
P003 C00S H00M 108.9 . . ?
H00L C00S H00M 107.7 . . ?
C00N C00T C017 117.87(12) . . ?
C00N C00T C01M 121.88(13) . . ?
C017 C00T C01M 120.25(13) . . ?
C017 C00U C00M 118.58(12) . . ?
C017 C00U C01H 119.35(12) . . ?
C00M C00U C01H 122.07(12) . . ?
C00H C00V C00B 118.51(12) . . ?
C00H C00V C01K 120.48(12) . . ?
C00B C00V C01K 120.97(12) . . ?
C00K C00W C013 117.92(12) . . ?
C00K C00W C01L 120.43(12) . . ?
C013 C00W C01L 121.63(12) . . ?
C00Q C00X C00J 121.72(12) . . ?
C00Q C00X H00X 119.1 . . ?
C00J C00X H00X 119.1 . . ?
C015 C00Y C00C 118.73(12) . . ?
C015 C00Y C00Z 121.05(12) . . ?
C00C C00Y C00Z 120.21(12) . . ?
C00Y C00Z H00O 109.5 . . ?
C00Y C00Z H00P 109.5 . . ?
H00O C00Z H00P 109.5 . . ?
C00Y C00Z H00Q 109.5 . . ?
H00O C00Z H00Q 109.5 . . ?
H00P C00Z H00Q 109.5 . . ?
C00A C010 H01A 109.5 . . ?
C00A C010 H01B 109.5 . . ?
H01A C010 H01B 109.5 . . ?
C00A C010 H01C 109.5 . . ?
H01A C010 H01C 109.5 . . ?
H01B C010 H01C 109.5 . . ?
C01F C011 P002 118.53(9) . . ?
C01F C011 H01D 107.7 . . ?
P002 C011 H01D 107.7 . . ?
C01F C011 H01E 107.7 . . ?
P002 C011 H01E 107.7 . . ?
H01D C011 H01E 107.1 . . ?
C00S C012 H01F 109.5 . . ?
C00S C012 H01G 109.5 . . ?
H01F C012 H01G 109.5 . . ?
C00S C012 H01H 109.5 . . ?
H01F C012 H01H 109.5 . . ?
H01G C012 H01H 109.5 . . ?
C00W C013 C00O 122.02(12) . . ?
C00W C013 H013 119.0 . . ?
C00O C013 H013 119.0 . . ?
C01G C014 P002 112.59(9) . . ?
C01G C014 H01I 109.1 . . ?
P002 C014 H01I 109.1 . . ?
C01G C014 H01J 109.1 . . ?
P002 C014 H01J 109.1 . . ?
H01I C014 H01J 107.8 . . ?
C00Y C015 C01D 121.65(13) . . ?
C00Y C015 H015 119.2 . . ?
C01D C015 H015 119.2 . . ?
C01O C016 P003 120.84(10) . . ?
C01O C016 H01K 107.1 . . ?
P003 C016 H01K 107.1 . . ?
C01O C016 H01L 107.1 . . ?
P003 C016 H01L 107.1 . . ?
H01K C016 H01L 106.8 . . ?
C00U C017 C00T 122.30(13) . . ?
C00U C017 H017 118.8 . . ?
C00T C017 H017 118.8 . . ?
C01B C018 N008 113.18(12) . . ?
C01B C018 H018 123.4 . . ?
N008 C018 H018 123.4 . . ?
C00Q C019 H01M 109.5 . . ?
C00Q C019 H01N 109.5 . . ?
H01M C019 H01N 109.5 . . ?
C00Q C019 H01O 109.5 . . ?
H01M C019 H01O 109.5 . . ?
H01N C019 H01O 109.5 . . ?
C00I C01A H01P 109.5 . . ?
C00I C01A H01Q 109.5 . . ?
H01P C01A H01Q 109.5 . . ?
C00I C01A H01R 109.5 . . ?
H01P C01A H01R 109.5 . . ?
H01Q C01A H01R 109.5 . . ?
C018 C01B N009 113.04(12) . . ?
C018 C01B H01S 123.5 . . ?
N009 C01B H01S 123.5 . . ?
C00O C01C H01T 109.5 . . ?
C00O C01C H01U 109.5 . . ?
H01T C01C H01U 109.5 . . ?
C00O C01C H01V 109.5 . . ?
H01T C01C H01V 109.5 . . ?
H01U C01C H01V 109.5 . . ?
C015 C01D C01E 118.41(12) . . ?
C015 C01D C01P 120.92(14) . . ?
C01E C01D C01P 120.67(14) . . ?
C01D C01E C00F 121.84(13) . . ?
C01D C01E H01W 119.1 . . ?
C00F C01E H01W 119.1 . . ?
C011 C01F H01X 109.5 . . ?
C011 C01F H01Y 109.5 . . ?
H01X C01F H01Y 109.5 . . ?
C011 C01F H01Z 109.5 . . ?
H01X C01F H01Z 109.5 . . ?
H01Y C01F H01Z 109.5 . . ?
C014 C01G H010 109.5 . . ?
C014 C01G H011 109.5 . . ?
H010 C01G H011 109.5 . . ?
C014 C01G H012 109.5 . . ?
H010 C01G H012 109.5 . . ?
H011 C01G H012 109.5 . . ?
C00U C01H H014 109.5 . . ?
C00U C01H H016 109.5 . . ?
H014 C01H H016 109.5 . . ?
C00U C01H H019 109.5 . . ?
H014 C01H H019 109.5 . . ?
H016 C01H H019 109.5 . . ?
C00L C01I H020 109.5 . . ?
C00L C01I H021 109.5 . . ?
H020 C01I H021 109.5 . . ?
C00L C01I H022 109.5 . . ?
H020 C01I H022 109.5 . . ?
H021 C01I H022 109.5 . . ?
C00J C01J H023 109.5 . . ?
C00J C01J H024 109.5 . . ?
H023 C01J H024 109.5 . . ?
C00J C01J H025 109.5 . . ?
H023 C01J H025 109.5 . . ?
H024 C01J H025 109.5 . . ?
C00V C01K H026 109.5 . . ?
C00V C01K H027 109.5 . . ?
H026 C01K H027 109.5 . . ?
C00V C01K H028 109.5 . . ?
H026 C01K H028 109.5 . . ?
H027 C01K H028 109.5 . . ?
C00W C01L H029 109.5 . . ?
C00W C01L H02A 109.5 . . ?
H029 C01L H02A 109.5 . . ?
C00W C01L H02B 109.5 . . ?
H029 C01L H02B 109.5 . . ?
H02A C01L H02B 109.5 . . ?
C00T C01M H02C 109.5 . . ?
C00T C01M H02D 109.5 . . ?
H02C C01M H02D 109.5 . . ?
C00T C01M H02E 109.5 . . ?
H02C C01M H02E 109.5 . . ?
H02D C01M H02E 109.5 . . ?
C00P C01N H02F 109.5 . . ?
C00P C01N H02G 109.5 . . ?
H02F C01N H02G 109.5 . . ?
C00P C01N H02H 109.5 . . ?
H02F C01N H02H 109.5 . . ?
H02G C01N H02H 109.5 . . ?
C016 C01O H02I 109.5 . . ?
C016 C01O H02J 109.5 . . ?
H02I C01O H02J 109.5 . . ?
C016 C01O H02K 109.5 . . ?
H02I C01O H02K 109.5 . . ?
H02J C01O H02K 109.5 . . ?
C01D C01P H02L 109.5 . . ?
C01D C01P H02M 109.5 . . ?
H02L C01P H02M 109.5 . . ?
C01D C01P H02N 109.5 . . ?
H02L C01P H02N 109.5 . . ?
H02M C01P H02N 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ni01 Si2 2.1451(4) . ?
Ni01 Si1 2.1541(4) . ?
Ni01 P002 2.1993(4) . ?
Ni01 P003 2.2029(4) . ?
Si1 N007 1.7646(11) . ?
Si1 N006 1.7809(11) . ?
P002 C014 1.8414(13) . ?
P002 C00P 1.8475(13) . ?
P002 C011 1.8609(13) . ?
Si2 N008 1.7671(11) . ?
Si2 N009 1.7774(11) . ?
P003 C00L 1.8411(13) . ?
P003 C00S 1.8546(13) . ?
P003 C016 1.8628(13) . ?
N006 C00G 1.4045(16) . ?
N006 C00D 1.4402(15) . ?
N007 C00E 1.3972(16) . ?
N007 C00C 1.4313(15) . ?
N008 C018 1.4004(17) . ?
N008 C00B 1.4381(16) . ?
N009 C01B 1.4017(16) . ?
N009 C00M 1.4381(16) . ?
C00A C00K 1.3928(17) . ?
C00A C00D 1.4012(18) . ?
C00A C010 1.5021(17) . ?
C00B C00V 1.3967(18) . ?
C00B C00J 1.4030(18) . ?
C00C C00F 1.3974(18) . ?
C00C C00Y 1.4062(18) . ?
C00D C00O 1.4059(18) . ?
C00E C00G 1.3351(18) . ?
C00E H00E 0.9500 . ?
C00F C01E 1.3949(18) . ?
C00F C00R 1.5099(18) . ?
C00G H00G 0.9500 . ?
C00H C00Q 1.3881(19) . ?
C00H C00V 1.3949(18) . ?
C00H H00H 0.9500 . ?
C00I C00N 1.3957(18) . ?
C00I C00M 1.4024(18) . ?
C00I C01A 1.5028(17) . ?
C00J C00X 1.3966(18) . ?
C00J C01J 1.5062(18) . ?
C00K C00W 1.3892(18) . ?
C00K H00K 0.9500 . ?
C00L C01I 1.5259(18) . ?
C00L H00A 0.9900 . ?
C00L H00B 0.9900 . ?
C00M C00U 1.4064(18) . ?
C00N C00T 1.3906(19) . ?
C00N H00N 0.9500 . ?
C00O C013 1.3918(18) . ?
C00O C01C 1.5096(18) . ?
C00P C01N 1.5276(18) . ?
C00P H00C 0.9900 . ?
C00P H00D 0.9900 . ?
C00Q C00X 1.3921(19) . ?
C00Q C019 1.5095(18) . ?
C00R H00F 0.9800 . ?
C00R H00I 0.9800 . ?
C00R H00J 0.9800 . ?
C00S C012 1.5268(18) . ?
C00S H00L 0.9900 . ?
C00S H00M 0.9900 . ?
C00T C017 1.393(2) . ?
C00T C01M 1.5096(19) . ?
C00U C017 1.3919(19) . ?
C00U C01H 1.5089(19) . ?
C00V C01K 1.5030(18) . ?
C00W C013 1.3920(19) . ?
C00W C01L 1.5062(18) . ?
C00X H00X 0.9500 . ?
C00Y C015 1.3895(18) . ?
C00Y C00Z 1.5059(18) . ?
C00Z H00O 0.9800 . ?
C00Z H00P 0.9800 . ?
C00Z H00Q 0.9800 . ?
C010 H01A 0.9800 . ?
C010 H01B 0.9800 . ?
C010 H01C 0.9800 . ?
C011 C01F 1.5309(18) . ?
C011 H01D 0.9900 . ?
C011 H01E 0.9900 . ?
C012 H01F 0.9800 . ?
C012 H01G 0.9800 . ?
C012 H01H 0.9800 . ?
C013 H013 0.9500 . ?
C014 C01G 1.5229(18) . ?
C014 H01I 0.9900 . ?
C014 H01J 0.9900 . ?
C015 C01D 1.392(2) . ?
C015 H015 0.9500 . ?
C016 C01O 1.5293(18) . ?
C016 H01K 0.9900 . ?
C016 H01L 0.9900 . ?
C017 H017 0.9500 . ?
C018 C01B 1.3370(19) . ?
C018 H018 0.9500 . ?
C019 H01M 0.9800 . ?
C019 H01N 0.9800 . ?
C019 H01O 0.9800 . ?
C01A H01P 0.9800 . ?
C01A H01Q 0.9800 . ?
C01A H01R 0.9800 . ?
C01B H01S 0.9500 . ?
C01C H01T 0.9800 . ?
C01C H01U 0.9800 . ?
C01C H01V 0.9800 . ?
C01D C01E 1.393(2) . ?
C01D C01P 1.5060(19) . ?
C01E H01W 0.9500 . ?
C01F H01X 0.9800 . ?
C01F H01Y 0.9800 . ?
C01F H01Z 0.9800 . ?
C01G H010 0.9800 . ?
C01G H011 0.9800 . ?
C01G H012 0.9800 . ?
C01H H014 0.9800 . ?
C01H H016 0.9800 . ?
C01H H019 0.9800 . ?
C01I H020 0.9800 . ?
C01I H021 0.9800 . ?
C01I H022 0.9800 . ?
C01J H023 0.9800 . ?
C01J H024 0.9800 . ?
C01J H025 0.9800 . ?
C01K H026 0.9800 . ?
C01K H027 0.9800 . ?
C01K H028 0.9800 . ?
C01L H029 0.9800 . ?
C01L H02A 0.9800 . ?
C01L H02B 0.9800 . ?
C01M H02C 0.9800 . ?
C01M H02D 0.9800 . ?
C01M H02E 0.9800 . ?
C01N H02F 0.9800 . ?
C01N H02G 0.9800 . ?
C01N H02H 0.9800 . ?
C01O H02I 0.9800 . ?
C01O H02J 0.9800 . ?
C01O H02K 0.9800 . ?
C01P H02L 0.9800 . ?
C01P H02M 0.9800 . ?
C01P H02N 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N007 Si1 N006 C00G -0.14(9) . . . . ?
Ni01 Si1 N006 C00G -179.89(7) . . . . ?
N007 Si1 N006 C00D 173.08(12) . . . . ?
Ni01 Si1 N006 C00D -6.67(16) . . . . ?
N006 Si1 N007 C00E 0.23(10) . . . . ?
Ni01 Si1 N007 C00E -179.99(7) . . . . ?
N006 Si1 N007 C00C -173.61(12) . . . . ?
Ni01 Si1 N007 C00C 6.17(14) . . . . ?
N009 Si2 N008 C018 1.79(10) . . . . ?
Ni01 Si2 N008 C018 -172.85(7) . . . . ?
N009 Si2 N008 C00B -166.17(11) . . . . ?
Ni01 Si2 N008 C00B 19.19(14) . . . . ?
N008 Si2 N009 C01B -1.49(10) . . . . ?
Ni01 Si2 N009 C01B 173.39(7) . . . . ?
N008 Si2 N009 C00M 160.78(11) . . . . ?
Ni01 Si2 N009 C00M -24.34(14) . . . . ?
C018 N008 C00B C00V 98.54(14) . . . . ?
Si2 N008 C00B C00V -93.82(14) . . . . ?
C018 N008 C00B C00J -79.01(15) . . . . ?
Si2 N008 C00B C00J 88.63(14) . . . . ?
C00E N007 C00C C00F 83.83(15) . . . . ?
Si1 N007 C00C C00F -102.37(13) . . . . ?
C00E N007 C00C C00Y -91.20(14) . . . . ?
Si1 N007 C00C C00Y 82.60(14) . . . . ?
C00K C00A C00D C00O 1.92(18) . . . . ?
C010 C00A C00D C00O -177.98(12) . . . . ?
C00K C00A C00D N006 175.36(11) . . . . ?
C010 C00A C00D N006 -4.53(18) . . . . ?
C00G N006 C00D C00A -103.44(13) . . . . ?
Si1 N006 C00D C00A 83.36(15) . . . . ?
C00G N006 C00D C00O 70.10(15) . . . . ?
Si1 N006 C00D C00O -103.10(14) . . . . ?
C00C N007 C00E C00G 174.54(12) . . . . ?
Si1 N007 C00E C00G -0.27(15) . . . . ?
C00Y C00C C00F C01E -1.23(19) . . . . ?
N007 C00C C00F C01E -176.17(11) . . . . ?
C00Y C00C C00F C00R 177.68(12) . . . . ?
N007 C00C C00F C00R 2.74(18) . . . . ?
N007 C00E C00G N006 0.15(17) . . . . ?
C00D N006 C00G C00E -174.60(12) . . . . ?
Si1 N006 C00G C00E 0.02(15) . . . . ?
C00V C00B C00J C00X 0.82(19) . . . . ?
N008 C00B C00J C00X 178.37(11) . . . . ?
C00V C00B C00J C01J -178.63(12) . . . . ?
N008 C00B C00J C01J -1.08(18) . . . . ?
C00D C00A C00K C00W -0.45(19) . . . . ?
C010 C00A C00K C00W 179.45(12) . . . . ?
C00S P003 C00L C01I 53.70(12) . . . . ?
C016 P003 C00L C01I -51.72(12) . . . . ?
Ni01 P003 C00L C01I -178.96(9) . . . . ?
C00N C00I C00M C00U 3.34(18) . . . . ?
C01A C00I C00M C00U -175.48(12) . . . . ?
C00N C00I C00M N009 -177.75(11) . . . . ?
C01A C00I C00M N009 3.42(18) . . . . ?
C01B N009 C00M C00I -112.24(14) . . . . ?
Si2 N009 C00M C00I 86.00(14) . . . . ?
C01B N009 C00M C00U 66.69(16) . . . . ?
Si2 N009 C00M C00U -95.08(13) . . . . ?
C00M C00I C00N C00T -0.93(19) . . . . ?
C01A C00I C00N C00T 177.90(12) . . . . ?
C00A C00D C00O C013 -2.19(18) . . . . ?
N006 C00D C00O C013 -175.74(11) . . . . ?
C00A C00D C00O C01C 177.73(12) . . . . ?
N006 C00D C00O C01C 4.18(18) . . . . ?
C014 P002 C00P C01N 166.42(10) . . . . ?
C011 P002 C00P C01N 65.20(11) . . . . ?
Ni01 P002 C00P C01N -64.28(10) . . . . ?
C00V C00H C00Q C00X -1.00(19) . . . . ?
C00V C00H C00Q C019 175.80(12) . . . . ?
C00L P003 C00S C012 59.74(10) . . . . ?
C016 P003 C00S C012 164.27(10) . . . . ?
Ni01 P003 C00S C012 -68.03(10) . . . . ?
C00I C00N C00T C017 -1.5(2) . . . . ?
C00I C00N C00T C01M 178.74(13) . . . . ?
C00I C00M C00U C017 -3.25(19) . . . . ?
N009 C00M C00U C017 177.82(12) . . . . ?
C00I C00M C00U C01H 176.29(12) . . . . ?
N009 C00M C00U C01H -2.63(19) . . . . ?
C00Q C00H C00V C00B 1.55(19) . . . . ?
C00Q C00H C00V C01K -176.41(12) . . . . ?
C00J C00B C00V C00H -1.44(18) . . . . ?
N008 C00B C00V C00H -178.95(11) . . . . ?
C00J C00B C00V C01K 176.51(12) . . . . ?
N008 C00B C00V C01K -1.00(18) . . . . ?
C00A C00K C00W C013 -0.71(19) . . . . ?
C00A C00K C00W C01L 177.86(12) . . . . ?
C00H C00Q C00X C00J 0.34(19) . . . . ?
C019 C00Q C00X C00J -176.44(12) . . . . ?
C00B C00J C00X C00Q -0.26(19) . . . . ?
C01J C00J C00X C00Q 179.20(12) . . . . ?
C00F C00C C00Y C015 0.96(18) . . . . ?
N007 C00C C00Y C015 175.93(11) . . . . ?
C00F C00C C00Y C00Z -179.76(12) . . . . ?
N007 C00C C00Y C00Z -4.78(17) . . . . ?
C014 P002 C011 C01F -62.53(12) . . . . ?
C00P P002 C011 C01F 39.09(12) . . . . ?
Ni01 P002 C011 C01F 171.48(9) . . . . ?
C00K C00W C013 C00O 0.4(2) . . . . ?
C01L C00W C013 C00O -178.13(13) . . . . ?
C00D C00O C013 C00W 1.0(2) . . . . ?
C01C C00O C013 C00W -178.91(12) . . . . ?
C00P P002 C014 C01G 69.67(10) . . . . ?
C011 P002 C014 C01G 172.71(10) . . . . ?
Ni01 P002 C014 C01G -62.00(10) . . . . ?
C00C C00Y C015 C01D -0.4(2) . . . . ?
C00Z C00Y C015 C01D -179.70(13) . . . . ?
C00L P003 C016 C01O 88.42(12) . . . . ?
C00S P003 C016 C01O -15.51(12) . . . . ?
Ni01 P003 C016 C01O -143.56(10) . . . . ?
C00M C00U C017 C00T 0.8(2) . . . . ?
C01H C00U C017 C00T -178.80(13) . . . . ?
C00N C00T C017 C00U 1.6(2) . . . . ?
C01M C00T C017 C00U -178.65(13) . . . . ?
C00B N008 C018 C01B 167.75(12) . . . . ?
Si2 N008 C018 C01B -1.73(16) . . . . ?
N008 C018 C01B N009 0.54(18) . . . . ?
C00M N009 C01B C018 -163.54(12) . . . . ?
Si2 N009 C01B C018 0.87(16) . . . . ?
C00Y C015 C01D C01E 0.2(2) . . . . ?
C00Y C015 C01D C01P -179.04(14) . . . . ?
C015 C01D C01E C00F -0.5(2) . . . . ?
C01P C01D C01E C00F 178.75(14) . . . . ?
C00C C00F C01E C01D 1.0(2) . . . . ?
C00R C00F C01E C01D -177.93(13) . . . . ?
