Information card for entry 1575932

Structure parameters

• Formula: C104 H91 K O5 Pr Si5
• Calculated formula: C104 H91 K O5 Pr Si5
• Title of publication: Accessing homoleptic neutral and anionic five-coordinate Pr(iv) siloxide complexes.
• Authors of publication: Pandey, Pragati; Keener, Megan; Rajeshkumar, Thayalan; Scopelliti, Rosario; Sienkiewicz, Andrzej; Zivkovic, Ivica; Maron, Laurent; Mazzanti, Marinella
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 44
• Pages of publication: 21056 - 21067
• a: 13.73996 ± 0.00012 Å
• b: 24.71494 ± 0.00017 Å
• c: 14.12364 ± 0.00013 Å
• α: 90°
• β: 113.975 ± 0.0011°
• γ: 90°
• Cell volume: 4382.36 ± 0.07 ų
• Cell temperature: 139.99 ± 0.1 K
• Ambient diffraction temperature: 139.99 ± 0.1 K
• Number of distinct elements: 6
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.046
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for significantly intense reflections: 0.1153
• Weighted residual factors for all reflections included in the refinement: 0.1155
• Goodness-of-fit parameter for all reflections included in the refinement: 1.163
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No