Information card for entry 1575975

Structure parameters

• Common name: Rh3
• Formula: C28 H43 B F4 N3 O4 Rh Si
• Calculated formula: C28 H43 B F4 N3 O4 Rh Si
• Title of publication: Confinement-induced Z-selectivity in the rhodium N-heterocyclic carbene-catalyzed hydroboration of terminal alkynes
• Authors of publication: Atwi, Boshra; Wang, Dongren; Bruckner, Johanna R.; Frey, Wolfgang; Buchmeiser, Michael R.
• Journal of publication: Catalysis Science & Technology
• Year of publication: 2025
• Journal volume: 15
• Journal issue: 23
• Pages of publication: 7059 - 7066
• a: 11.089 ± 0.002 Å
• b: 12.165 ± 0.003 Å
• c: 14.201 ± 0.005 Å
• α: 99.026 ± 0.008°
• β: 101.031 ± 0.008°
• γ: 116.881 ± 0.006°
• Cell volume: 1611 ± 0.8 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0669
• Residual factor for significantly intense reflections: 0.0473
• Weighted residual factors for significantly intense reflections: 0.1136
• Weighted residual factors for all reflections included in the refinement: 0.1236
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No