Information card for entry 1575983

Structure parameters

• Formula: C59 H144 Ce Mo2 N5 O39 W8
• Calculated formula: C59 H144 Ce Mo2 N5 O39 W8
• Title of publication: Isolation of Ce(iv) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency.
• Authors of publication: Shiels, Dominic; Pittalis, Michele; Gunarathna, Nadeeshan; Berlfein, Adriana C.; Brennessel, William W.; Ruggiero, Michael T.; Matson, Ellen M.
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 46
• Pages of publication: 21917 - 21931
• a: 13.11989 ± 0.00007 Å
• b: 14.37437 ± 0.0001 Å
• c: 25.938 ± 0.0002 Å
• α: 77.006 ± 0.0006°
• β: 89.2214 ± 0.0005°
• γ: 75.4995 ± 0.0005°
• Cell volume: 4609.83 ± 0.06 ų
• Cell temperature: 100.01 ± 0.1 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0298
• Residual factor for significantly intense reflections: 0.0287
• Weighted residual factors for significantly intense reflections: 0.0627
• Weighted residual factors for all reflections included in the refinement: 0.0632
• Goodness-of-fit parameter for all reflections included in the refinement: 1.108
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No