Information card for entry 1576049

Structure parameters

• Chemical name: [Rh(dtbq)2Me2-bpy](PF6)
• Formula: C109 H76 Cl10 F12 N12 P2 Rh2 S8
• Calculated formula: C109 H76 Cl10 F12 N12 P2 Rh2 S8
• Title of publication: Rhodamine-functionalised rhodium(iii) complexes: dual role as bioimaging agents and controllable reactive oxygen species photosensitisers for photocytotoxicity applications.
• Authors of publication: Jiang, Katherine Gui-Min; Wei, Fangfang; Leung, Peter Kam-Keung; Wu, Siye; Lo, Kenneth Kam-Wing; Wong, Keith Man-Chung
• Journal of publication: Chemical science
• Year of publication: 2025
• Journal volume: 16
• Journal issue: 46
• Pages of publication: 22127 - 22135
• a: 12.9995 ± 0.0005 Å
• b: 13.8501 ± 0.0005 Å
• c: 16.0709 ± 0.0006 Å
• α: 82.958 ± 0.002°
• β: 86.247 ± 0.003°
• γ: 74.635 ± 0.002°
• Cell volume: 2767.36 ± 0.18 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100.17 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0674
• Residual factor for significantly intense reflections: 0.052
• Weighted residual factors for significantly intense reflections: 0.1333
• Weighted residual factors for all reflections included in the refinement: 0.1449
• Goodness-of-fit parameter for all reflections included in the refinement: 1.063
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No