Information card for entry 1576236

Structure parameters

• Formula: C23.1 H24.1 F27.9 Mo2 O8 Si0.9
• Calculated formula: C23.1 H24.1 F27.9 Mo2 O8 Si0.9
• Title of publication: Initiating olefin metathesis: alkylidenes from molecular Mo(iv)-oxo species, olefins and base-promoted proton transfer
• Authors of publication: Nater, Darryl F.; de Zwart, Felix J.; Kaeffer, Nicolas; Copéret, Christophe
• Journal of publication: Chemical Science
• Year of publication: 2025
• a: 10.8082 ± 0.0004 Å
• b: 17.7991 ± 0.0005 Å
• c: 10.1192 ± 0.0004 Å
• α: 90°
• β: 110.743 ± 0.004°
• γ: 90°
• Cell volume: 1820.51 ± 0.12 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.088
• Residual factor for significantly intense reflections: 0.0839
• Weighted residual factors for significantly intense reflections: 0.2282
• Weighted residual factors for all reflections included in the refinement: 0.2358
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No