Information card for entry 1576787

Structure parameters

• Formula: C108 H147 La S3
• Calculated formula: C108 H147 La S3
• Title of publication: Unexpected dispersion-stabilized tris(terphenylthiolate) complexes, Ln(SAriPr6)3, arising from two-electron reduction by Ln(SAriPr6)2 [AriPr6 = C6H3-2,6-(C6H2-2,6,4-iPr3)2]
• Authors of publication: Luevano, Makayla R.; Stennett, Cary R.; Ma, Eric; Ziller, Joseph W.; Furche, Filipp; Evans, William J.
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 14.8533 ± 0.001 Å
• b: 44.125 ± 0.003 Å
• c: 16.4431 ± 0.0011 Å
• α: 90°
• β: 100.232 ± 0.001°
• γ: 90°
• Cell volume: 10605.4 ± 1.2 ų
• Cell temperature: 100.11 K
• Ambient diffraction temperature: 100.11 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.082
• Residual factor for significantly intense reflections: 0.0521
• Weighted residual factors for significantly intense reflections: 0.1046
• Weighted residual factors for all reflections included in the refinement: 0.1136
• Goodness-of-fit parameter for all reflections included in the refinement: 1.02
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No