Information card for entry 1577141

Structure parameters

• Formula: C56.75 H66.75 B Cl2 F24 P2 Rh
• Calculated formula: C53 H58 B Cl2 F24 P2 Rh
• Title of publication: The Characterisation and Reactivity of a Rh III η1 -σ-Alkane Complex and the Role of a Structurally Responsive Phosphine Ligand in Solid-State Molecular Organometallic Chemistry
• Authors of publication: Goodall, Joe; Sajjad, M. Arif; Furfari, Samantha Kathleen; Hatcher, Theo S.; Weller, Andrew S.; Macgregor, Stuart Alan; Lynam, Jason Martin; Warren, Mark R.; Page, Samuel J.; Tizzard, Graham J.; Altus, Kris Mark
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 21.7026 ± 0.0001 Å
• b: 27.8126 ± 0.0001 Å
• c: 21.4855 ± 0.0001 Å
• α: 90°
• β: 103.089 ± 0.001°
• γ: 90°
• Cell volume: 12631.8 ± 0.11 ų
• Cell temperature: 110.05 ± 0.1 K
• Ambient diffraction temperature: 110.05 ± 0.1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0643
• Residual factor for significantly intense reflections: 0.0595
• Weighted residual factors for significantly intense reflections: 0.1636
• Weighted residual factors for all reflections included in the refinement: 0.1678
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0383
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No