Information card for entry 1577417

Structure parameters

• Formula: C17 H20 F2 O Si
• Calculated formula: C17 H20 F2 O Si
• Title of publication: Rhodium-Catalyzed Enantioselective Intermolecular C–H Silylation of Simple Arenes: Synergistic Substituent Effects Overcome Silane Redistribution to Enable Synthesis of Si-Stereogenic Arylsilanes
• Authors of publication: Liu, Lichuan; Chen, Xingliang; Guan, Guiyu; Su, Xinyue; Liu, Mengqing; Hu, Yuefei; He, Wei; Zhang, Linxing; Ma, Wenpeng; An, Kun
• Journal of publication: Chemical Science
• Year of publication: 2026
• a: 9.5297 ± 0.0002 Å
• b: 8.1356 ± 0.0002 Å
• c: 11.0854 ± 0.0003 Å
• α: 90°
• β: 108.274 ± 0.002°
• γ: 90°
• Cell volume: 816.11 ± 0.04 ų
• Cell temperature: 180 ± 0.1 K
• Ambient diffraction temperature: 180 ± 0.1 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0319
• Residual factor for significantly intense reflections: 0.0289
• Weighted residual factors for significantly intense reflections: 0.0784
• Weighted residual factors for all reflections included in the refinement: 0.0859
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No