Information card for entry 2006450

Structure parameters

• Common name: [Mo(CO)(dpepp)(dppm)] (dppm = Ph~2~PCH~2~PPh~2~, dpepp = Ph~2~PCH~2~CH~2~P(Ph)CH~2~CH~2~PPh~2~)
• Chemical name: carbonyl[bis[2-(diphenylphosphino)ethyl)]phenylphosphine- P,P',P''][methylenebis(diphenylphosphino)- P,P']molybdenum(0)
• Formula: C60 H55 Mo O P5
• Calculated formula: C60 H55 Mo O P5
• Title of publication: [Mo(C~25~H~22~P~2~)(C~34~H~33~P~3~)(CO)]
• Authors of publication: George, T. Adrian; DeBord, Jeffrey R. D.; Heier, Kevin; Tisdale, Robert C.; Davies, Marcia C.; Haas, Eric J.; Ross II, Charles R.; Stezowski, John J.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1997
• Journal volume: 53
• Journal issue: 9
• Pages of publication: 1251 - 1254
• a: 12.108 ± 0.002 Å
• b: 12.155 ± 0.002 Å
• c: 18.884 ± 0.004 Å
• α: 104.37 ± 0.03°
• β: 100.67 ± 0.03°
• γ: 100.8 ± 0.03°
• Cell volume: 2565 ± 1 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0821
• Residual factor for significantly intense reflections: 0.051
• Weighted residual factors for all reflections: 0.134
• Weighted residual factors for significantly intense reflections: 0.116
• Goodness-of-fit parameter for all reflections: 1.02
• Goodness-of-fit parameter for significantly intense reflections: 1.05
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No