Information card for entry 2008478

Structure parameters

• Chemical name: cis-dihydridotetrakis(trimethylphosphine)rhodium(III) bis(catecholato)borate
• Formula: C24 H46 B O4 P4 Rh
• Calculated formula: C24 H46 B O4 P4 Rh
• Title of publication: Salts of the bis(catecholato)borate anion with rhodium‒ and iridium‒phosphine complex cations
• Authors of publication: Clegg, William; Elsegood, Mark R.J.; Scott, Andrew J.; Marder, Todd B.; Dai, Chaoyang; Norman, Nicholas C.; Pickett, Nigel L.; Robins, Edward G.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 1999
• Journal volume: 55
• Journal issue: 5
• Pages of publication: 733 - 739
• a: 13.4442 ± 0.0007 Å
• b: 18.7746 ± 0.001 Å
• c: 24.5809 ± 0.0012 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 6204.5 ± 0.6 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.1043
• Residual factor for significantly intense reflections: 0.0878
• Weighted residual factors for all reflections included in the refinement: 0.1903
• Goodness-of-fit parameter for all reflections included in the refinement: 1.448
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No