Information card for entry 2010897

Structure parameters

• Chemical name: Bis(μ-3,11-diethyl-6,8-diphenyl-3,6,8,11-tetraphosphatridecane- κ^4^-P^3^,P^6^:P^8^,P^11^)dirhodium(I) bis(tetrafluoroborate)
• Formula: C50 H80 B2 F8 P8 Rh2
• Calculated formula: C50 H80 B2 F8 P8 Rh2
• SMILES: [Rh]123[P](CC[P]2(C[P]2([Rh]4([P](C[P]3(CC[P]1(CC)CC)c1ccccc1)(c1ccccc1)CC[P]4(CC)CC)[P](CC2)(CC)CC)c1ccccc1)c1ccccc1)(CC)CC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-]
• Title of publication: A binuclear rhodium(I) complex with two tetraphosphine ligands at 100K
• Authors of publication: Hunt Jr, Clinton; Nelson, Brent D.; Harmon, Elisa G.; Fronczek, Frank R.; Watkins, Steven F.; Billodeaux, Damon R.; Stanley, George G.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2000
• Journal volume: 56
• Journal issue: 5
• Pages of publication: 546 - 548
• a: 15.651 ± 0.003 Å
• b: 16.048 ± 0.003 Å
• c: 24.022 ± 0.005 Å
• α: 90°
• β: 108.18 ± 0.03°
• γ: 90°
• Cell volume: 5732 ± 2 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.049
• Residual factor for significantly intense reflections: 0.038
• Weighted residual factors for all reflections: 0.095
• Weighted residual factors for significantly intense reflections: 0.089
• Goodness-of-fit parameter for all reflections: 1.04
• Goodness-of-fit parameter for significantly intense reflections: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes