Information card for entry 2012330

Structure parameters

• Chemical name: [6-carbonyl-6,6-bis(triphenylphosphine)-nido-6-osmadecaborane(13)]
• Formula: C37 H43 B9 O Os P2
• Calculated formula: C37 H41 B9 O Os P2
• Title of publication: The <i>nido</i>‒osmaboranes [2,2,2-(CO)(PPh~3~)~2~-<i>nido</i>-2-OsB~5~H~9~] and [6,6,6-(CO)(PPh~3~)~2~-<i>nido</i>-6-OsB~9~H~13~]
• Authors of publication: Bould, Jonathan; Kennedy, John D.; Thomas, Rhodri Ll.; Rath, Nigam P.; Barton, Lawrence
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2001
• Journal volume: 57
• Journal issue: 11
• Pages of publication: 1245 - 1247
• a: 10.4617 ± 0.0001 Å
• b: 15.6821 ± 0.0001 Å
• c: 22.6315 ± 0.0003 Å
• α: 90°
• β: 91.08 ± 0.01°
• γ: 90°
• Cell volume: 3712.3 ± 0.07 ų
• Cell temperature: 223 ± 2 K
• Ambient diffraction temperature: 223 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.084
• Residual factor for significantly intense reflections: 0.057
• Weighted residual factors for all reflections included in the refinement: 0.116
• Goodness-of-fit parameter for all reflections included in the refinement: 1.179
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes