Information card for entry 2014504

Structure parameters

• Chemical name: catena-poly[[[acetonitrilesilver(I)]-di-μ-4-[N- (diphenylphosphino)aminomethyl]pyridine-κ^2^N^1^:P;κ^2^P:N^1^- [acetonitrilesilver(I)]-μ~3~- 4-[N,N-bis(diphenylphosphino)aminomethyl]pyridine-κ^3^N^1^:P:P'- bis[acetonitrilesilver(I)(Ag—Ag)]-μ~3~-4-[N,N- bis(diphenylphosphino)aminomethyl]pyridine-κ^3^P:P':N^1^] tetrakis(tetrafluoroborate) acetonitrile trisolvate]
• Formula: C116 H116 Ag4 B4 F16 N16 P6
• Calculated formula: C116 H116 Ag4 B4 F16 N18 P6
• SMILES: [Ag]1([n]2ccc(cc2)CN([P](c2ccccc2)(c2ccccc2)[Ag]2[N]#CC)[P](c3ccccc3)(c3ccccc3)[Ag]([N]#CC)[P](c3ccccc3)(c3ccccc3)N([P]2(c2ccccc2)c2ccccc2)Cc2cc[n](cc2)[Ag]2([N]#CC)[P](NCc3cc[n](cc3)[Ag]([N]#CC)[P](NCc3cc[n]2cc3)(c2ccccc2)c2ccccc2)(c2ccccc2)c2ccccc2)([N]#CC)[P](c2ccccc2)(c2ccccc2)NCc2cc[n](cc2)[Ag]([N]#CC)([P](NCc2cc[n]1cc2)(c1ccccc1)c1ccccc1)[n]1ccc(cc1)CN([P](c1ccccc1)(c1ccccc1)[Ag]1[N]#CC)[P](c2ccccc2)(c2ccccc2)[Ag]([N]#CC)[P](c2ccccc2)(c2ccccc2)N([P]1(c1ccccc1)c1ccccc1)Cc1ccncc1.N#CC.N#CC.N#CC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-].N#CC.N#CC.N#CC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-].N#CC.N#CC.N#CC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-].N#CC.N#CC.N#CC.[B](F)(F)(F)[F-].[B](F)(F)(F)[F-]
• Title of publication: Self-assembly of a mixed-ligand silver-based coordination polymer
• Authors of publication: Feazell, Rodney P.; Carson, Cody E.; Klausmeyer, Kevin K.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2004
• Journal volume: 60
• Journal issue: 11
• Pages of publication: m598 - m600
• a: 13.2233 ± 0.0008 Å
• b: 14.6535 ± 0.0011 Å
• c: 16.7275 ± 0.0012 Å
• α: 97.085 ± 0.002°
• β: 104.69 ± 0.002°
• γ: 101.691 ± 0.003°
• Cell volume: 3017.6 ± 0.4 ų
• Cell temperature: 110 ± 2 K
• Ambient diffraction temperature: 110 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0647
• Residual factor for significantly intense reflections: 0.0377
• Weighted residual factors for significantly intense reflections: 0.0735
• Weighted residual factors for all reflections included in the refinement: 0.081
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes