Information card for entry 2016443

Structure parameters

• Chemical name: (dibenzoylmethylene-κ<i>C</i>)(ethanol-κ<i>O</i>){5,10,15,20- tetrakis[(1<i>S</i>,4<i>R</i>,5<i>R</i>,8<i>S</i>)-1,2,3,4,5,6,7,8-octahydro- 1,4:5,8-dimethanoanthracen-9-yl]porphyrinato-κ^4^<i>N</i>}ruthenium(II)‒ ethanol‒dichloromethane (1/2/2)
• Formula: C107 H108 Cl4 N4 O5 Ru
• Calculated formula: C107 H108 Cl4 N4 O5 Ru
• Title of publication: Enantiomorphs of a carbene‒ruthenium(II)‒porphyrin complex with four `chiral pillars'
• Authors of publication: Hirasawa, Kai; Yuge, Hidetaka; Miyamoto, Takeshi Ken
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2008
• Journal volume: 64
• Journal issue: 2
• Pages of publication: m97 - m100
• a: 13.7461 ± 0.0018 Å
• b: 23.674 ± 0.003 Å
• c: 26.781 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8715.2 ± 1.9 ų
• Cell temperature: 120 ± 1 K
• Ambient diffraction temperature: 120 ± 1 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0661
• Residual factor for significantly intense reflections: 0.0572
• Weighted residual factors for significantly intense reflections: 0.1275
• Weighted residual factors for all reflections included in the refinement: 0.1343
• Goodness-of-fit parameter for all reflections included in the refinement: 1.096
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes