Information card for entry 2017695

Structure parameters

• Common name: (salen)chromium(V)-(μ-nitrido)-chloro(COD)rhodium(I)
• Chemical name: chlorido-2κ<i>Cl</i>-[2(η^4^)-1,5-cyclooctadiene]{2,2'-[ethane-1,2- diylbis(nitrilomethylidyne)]diphenolato- 1κ^4^<i>O</i>,<i>N</i>,<i>N</i>',<i>O</i>'}-μ-nitrido- 1:2κ^2^<i>N</i>:<i>N</i>-chromium(V)rhodium(I)
• Formula: C24 H26 Cl Cr N3 O2 Rh
• Calculated formula: C24 H26 Cl Cr N3 O2 Rh
• SMILES: [Rh]123(Cl)(N=[Cr]456[N](=Cc7c(O5)cccc7)CC[N]4=Cc4ccccc4O6)[CH]4CC[CH]1=[CH]2CC[CH]3=4
• Title of publication: Synthesis and molecular structure of Cr(salen)(μ-N)RhCl(COD): the first example of a heterobimetallic nitride-bridged complex containing chromium
• Authors of publication: Vibenholt, Johan; Magnussen, Magnus; Anthon, Christian; Bendix, Jesper
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2010
• Journal volume: 66
• Journal issue: 7
• Pages of publication: m177 - m179
• a: 12.614 ± 0.0013 Å
• b: 15.1085 ± 0.0014 Å
• c: 12.6704 ± 0.0017 Å
• α: 90°
• β: 107.259 ± 0.01°
• γ: 90°
• Cell volume: 2306 ± 0.5 ų
• Cell temperature: 122 ± 1 K
• Ambient diffraction temperature: 122 ± 1 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0458
• Residual factor for significantly intense reflections: 0.0294
• Weighted residual factors for significantly intense reflections: 0.0607
• Weighted residual factors for all reflections included in the refinement: 0.0667
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes