Information card for entry 2018293

Structure parameters

• Chemical name: (dimethylamine‒dimethylaminoborane‒borane- κ^2^<i>H</i>,<i>H</i>')dihydridobis(triisopropylphosphane- κ<i>P</i>)rhodium(III) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate
• Formula: C54 H74 B3 F24 N2 P2 Rh
• Calculated formula: C54 H74 B3 F24 N2 P2 Rh
• Title of publication: A rhodium(III) complex of the linear diborazine H~3~B·NMe~2~BH~2~·NMe~2~H: an intermediate in the dehydrocoupling of H~3~B·NMe~2~H
• Authors of publication: Chaplin, Adrian B.; Weller, Andrew S.
• Journal of publication: Acta Crystallographica Section C
• Year of publication: 2011
• Journal volume: 67
• Journal issue: 11
• Pages of publication: m355 - m358
• a: 12.8309 ± 0.0002 Å
• b: 14.0813 ± 0.0002 Å
• c: 19.1638 ± 0.0003 Å
• α: 73.0175 ± 0.0006°
• β: 76.4127 ± 0.0005°
• γ: 86.6877 ± 0.0006°
• Cell volume: 3218.56 ± 0.09 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0612
• Residual factor for significantly intense reflections: 0.0472
• Weighted residual factors for significantly intense reflections: 0.1192
• Weighted residual factors for all reflections included in the refinement: 0.1293
• Goodness-of-fit parameter for all reflections included in the refinement: 1.015
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes