Information card for entry 2019848

Structure parameters

• Chemical name: [1-(2,6-Diisopropylphenyl)-2,4-bis(dimethylamino)-5-trimethylsilyl-1,3,5-triazapentadienyl-κ^2^<i>N</i>^1^,<i>N</i>^5^](triphenylphosphane-κ<i>P</i>)copper(I)
• Formula: C39 H53 Cu N5 P Si
• Calculated formula: C39 H53 Cu N5 P Si
• SMILES: [Cu]1([N](c2c(cccc2C(C)C)C(C)C)=C(N=C(N1[Si](C)(C)C)N(C)C)N(C)C)[P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Crystal structure of [1-(2,6-diisopropylphenyl)-2,4-bis(dimethylamino)-5-trimethylsilyl-1,3,5-triazapentadienyl-κ2N1,N5](triphenylphosphane-κP)copper(I)
• Authors of publication: Li, Feiguang; Yan, Lei; Tong, Hongbo; Zhou, Meisu
• Journal of publication: Acta Crystallographica Section E Crystallographic Communications
• Year of publication: 2015
• Journal volume: 71
• Journal issue: 3
• Pages of publication: m54
• a: 9.7935 ± 0.0016 Å
• b: 11.2141 ± 0.0018 Å
• c: 19.57 ± 0.003 Å
• α: 103.601 ± 0.004°
• β: 90.867 ± 0.003°
• γ: 108.24 ± 0.004°
• Cell volume: 1974.9 ± 0.5 ų
• Cell temperature: 195 ± 2 K
• Ambient diffraction temperature: 195 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1189
• Residual factor for significantly intense reflections: 0.0509
• Weighted residual factors for significantly intense reflections: 0.0748
• Weighted residual factors for all reflections included in the refinement: 0.0891
• Goodness-of-fit parameter for all reflections included in the refinement: 0.749
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes