Information card for entry 2022847

Structure parameters

• Chemical name: {(<i>R</i>)-1-[1-(Dimethylamino)ethyl]napthyl-κ^2^<i>N</i>,<i>C</i>^2^}[(diphenylphosphanylmethyl)diphenylphosphine sulfide-κ^2^<i>P</i>,<i>S</i>]platinum(II) hexafluoridoantimonate dichloromethane monosolvate
• Formula: C40 H40 Cl2 F6 N P2 Pt S Sb
• Calculated formula: C39 H38 F6 N P2 Pt S Sb
• SMILES: [Pt]12([S]=P(C[P]1(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[N]([C@@H](c1c2ccc2ccccc12)C)(C)C.[Sb](F)(F)(F)(F)(F)[F-]
• Title of publication: Hemilability and structural considerations in complexes of platinum(II) comprising bis(diphenylphosphanyl)methane monoxide, monosulfide, and monoselenide
• Authors of publication: Faller, Jack; Parr, Jonathan
• Journal of publication: Acta Crystallographica Section C Structural Chemistry
• Year of publication: 2023
• Journal volume: 79
• Journal issue: 9
• a: 12.9774 ± 0.0008 Å
• b: 18.3039 ± 0.0011 Å
• c: 18.2877 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4344 ± 0.5 ų
• Cell temperature: 223.1 K
• Ambient diffraction temperature: 223.1 K
• Number of distinct elements: 9
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0779
• Residual factor for significantly intense reflections: 0.0544
• Weighted residual factors for significantly intense reflections: 0.0974
• Weighted residual factors for all reflections included in the refinement: 0.105
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes