Information card for entry 2200800

Structure parameters

• Chemical name: 1,4:2,3-bis(μ-2,4,6-trimethylphenyl-C:C)-1,2:3,4-bis[μ- bis(trimethylsilyl)amido-N:N]tetracopper(I)
• Formula: C30 H58 Cu4 N2 Si4
• Calculated formula: C30 H58 Cu4 N2 Si4
• SMILES: [Cu]123[Cu]4([Cu]5([Cu]1([N]5([Si](C)(C)C)[Si](C)(C)C)[c]13c(cc(cc1C)C)C)[c]14c(cc(cc1C)C)C)[N]2([Si](C)(C)C)[Si](C)(C)C
• Title of publication: A heteroleptic tetranuclear copper amide/aryl complex: 1,4:2,3-bis(μ-2,4,6-trimethylphenyl-<i>C</i>,<i>C</i>)-1,2:3,4-bis[μ-bis(trimethylsilyl)amido-<i>N</i>,<i>N</i>]tetracopper(I)
• Authors of publication: Niemeyer, Mark
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2001
• Journal volume: 57
• Journal issue: 10
• Pages of publication: m491 - m493
• a: 9.171 ± 0.002 Å
• b: 11.353 ± 0.002 Å
• c: 20.314 ± 0.004 Å
• α: 101.98 ± 0.01°
• β: 94.56 ± 0.02°
• γ: 107.28 ± 0.02°
• Cell volume: 1952.9 ± 0.7 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.047
• Residual factor for significantly intense reflections: 0.037
• Weighted residual factors for all reflections included in the refinement: 0.101
• Goodness-of-fit parameter for all reflections included in the refinement: 1.07
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes