Information card for entry 2201519

Structure parameters

• Common name: silver[tris(2,3,5,6)-tetraphenylphenoxy)germanium(II) silver(I) trifluorormethanesulfonate] tetrabenzene
• Chemical name: tris[μ-2,6-diphenylphenoxy(1-)-1:3κ^2^O,1κC^2^](trifluoromethylsulfonato- 2κO)disilvergermanium (Ag–Ge) tetrabenzene solvate
• Formula: C115 H87 Ag2 F3 Ge O6 S
• Calculated formula: C115 H87 Ag2 F3 Ge O6 S
• SMILES: [Ag+].[Ag]([Ge](Oc1c(c2ccccc2)c(cc(c1c1ccccc1)c1ccccc1)c1ccccc1)(Oc1c(c(cc(c1c1ccccc1)c1ccccc1)c1ccccc1)c1ccccc1)Oc1c(c(cc(c1c1ccccc1)c1ccccc1)c1ccccc1)c1ccccc1)OS(=O)(=O)C(F)(F)F.c1ccccc1.c1ccccc1.c1ccccc1.c1ccccc1
• Title of publication: A germanium–silver complex containing aGe—Ag bond, Ag[Ge(OC~6~HPh~4~-2,3,5,6)~3~(AgOSO~2~CF~3~)]·4C~6~H~6~
• Authors of publication: Charles S. Weinert; Phillip E. Fanwick; Ian P. Rothwell
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2002
• Journal volume: 58
• Journal issue: 12
• Pages of publication: m718 - m720
• a: 13.9593 ± 0.0002 Å
• b: 24.3433 ± 0.0003 Å
• c: 26.9406 ± 0.0004 Å
• α: 90°
• β: 92.1511 ± 0.0005°
• γ: 90°
• Cell volume: 9148.4 ± 0.2 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.039
• Weighted residual factors for all reflections included in the refinement: 0.074
• Goodness-of-fit parameter for all reflections included in the refinement: 0.912
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes