Information card for entry 2201863

Structure parameters

• Chemical name: μ-trimethylsilylethynyl-μ-trimethylsilylethynethiolato- pentadecacarbonyldicobalttriruthenium
• Formula: C25 H18 Co2 O15 Ru3 S Si2
• Calculated formula: C25 H18 Co2 O15 Ru3 S Si2
• SMILES: [Ru]12(C#[O])(C#[O])(C#[O])[C]([Ru]134(C#[O])(C#[O])C#[O])(=[C]13[Si](C)(C)C)[Ru]12(C#[O])(C#[O])(C#[O])[S]4[C]12[Co]3(C#[O])(C#[O])(C#[O])[C]=1([Co]23(C#[O])(C#[O])C#[O])[Si](C)(C)C
• Title of publication: Hexacarbonyldicobalt addition across the C[tripleC bond of the alkynethiolate ligand in the cluster [Ru~3~(μ~3~,η^2^-C[tripleCSiMe~3~)(μ-SC[tripleCSiMe~3~)(CO)~9~]
• Authors of publication: Esther Delgado; M. Isabel Alcade; Bruno Donnadieu; Elisa Hernandez; Javier Sanchez-Nieves
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2003
• Journal volume: 59
• Journal issue: 4
• Pages of publication: m207 - m209
• a: 9.2407 ± 0.001 Å
• b: 12.0579 ± 0.0013 Å
• c: 18.841 ± 0.002 Å
• α: 75.882 ± 0.013°
• β: 87.813 ± 0.014°
• γ: 69.403 ± 0.012°
• Cell volume: 1903.2 ± 0.4 ų
• Cell temperature: 180 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0316
• Weighted residual factors for all reflections included in the refinement: 0.0944
• Goodness-of-fit parameter for all reflections included in the refinement: 1.106
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes