Information card for entry 2203900

Structure parameters

• Chemical name: {(carbonyl)(acetonitrilo)(μ~2~-O)(P)(dibenzo-[d,f]-2,2,4,4-tetra-tert-butyl- [1,3,2]dioxa-phosphito)}-rhodium(I)-dimer ∼1.5 dichloromethane solvate
• Formula: C62 H86 N2 O8 P2 Rh2
• Calculated formula: C62 H86 N2 O8 P2 Rh2
• Title of publication: Bis[μ-3,3',5,5'-tetra-<i>tert</i>-butylbiphenyl-2,2'-diyl phosphonato(1‒)]bis[(acetonitrile)carbonylrhodium(I)] dichloromethane sesquisolvate
• Authors of publication: Tooke, Duncan M.; Mills, Allison M.; Spek, Anthony L.; van der Vlugt, Jarl Ivar; Vogt, Dieter
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2004
• Journal volume: 60
• Journal issue: 7
• Pages of publication: m943 - m945
• a: 29.2584 ± 0.0004 Å
• b: 12.4252 ± 0.0002 Å
• c: 21.724 ± 0.0003 Å
• α: 90°
• β: 118.355 ± 0.0005°
• γ: 90°
• Cell volume: 6950.05 ± 0.18 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0673
• Residual factor for significantly intense reflections: 0.0434
• Weighted residual factors for significantly intense reflections: 0.0911
• Weighted residual factors for all reflections included in the refinement: 0.0981
• Goodness-of-fit parameter for all reflections included in the refinement: 1.045
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes