Information card for entry 2204622

Structure parameters

• Chemical name: (μ~2~-phosphindolyl)(μ~2~-1-phenyl-phosphind-2-yl-C,P)bis(manganese- tetracarbonyl)
• Formula: C30 H16 Mn2 O8 P2
• Calculated formula: C30 H16 Mn2 O8 P2
• SMILES: [Mn]1([P]2([Mn](C#[O])(C#[O])(C#[O])(C#[O])C3=Cc4ccccc4[P]13c1ccccc1)C=Cc1ccccc21)(C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: A novel coordination mode for a phospholyl ligand: μ-phosphindolyl-κ^2^<i>P</i>:<i>P</i>-μ-1-phenyl-phosphindolyl-κ^2^<i>C</i>^2^:<i>P</i>-bis[tetracarbonylmanganese(I)]
• Authors of publication: Andreas Decken; Wilkins, Brianne E.; Bottomley, Frank
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2004
• Journal volume: 60
• Journal issue: 12
• Pages of publication: m1985 - m1986
• a: 20.681 ± 0.002 Å
• b: 9.885 ± 0.0009 Å
• c: 28.44 ± 0.002 Å
• α: 90°
• β: 100.368 ± 0.004°
• γ: 90°
• Cell volume: 5719.1 ± 0.9 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 1 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.1235
• Residual factor for significantly intense reflections: 0.0723
• Weighted residual factors for significantly intense reflections: 0.169
• Weighted residual factors for all reflections included in the refinement: 0.1811
• Goodness-of-fit parameter for all reflections included in the refinement: 0.966
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes