Information card for entry 2207335

Structure parameters

• Common name: rhodium cod thiolate dimer
• Chemical name: Bis[μ-2,3,5,6-tetrafluoro-4-(trifluoromethyl)benzenethiolato]bis[(η^4^-3,5- cyclooctadiene)rhodium(I)]
• Formula: C30 H24 F14 Rh2 S2
• Calculated formula: C30 H24 F14 Rh2 S2
• SMILES: [Rh]2345([S](c1c(F)c(F)c(c(F)c1F)C(F)(F)F)[Rh]678([S]2c1c(F)c(F)c(c(F)c1F)C(F)(F)F)[CH]1=[CH]6CC[CH]7=[CH]8CC1)[CH]1=[CH]3CC[CH]4=[CH]5CC1
• Title of publication: Bis[μ-2,3,5,6-tetrafluoro-4-(trifluoromethyl)benzenethiolato]bis[(η^4^-3,5-cyclooctadiene)rhodium(I)]
• Authors of publication: Jones, William D.; Garcia, Juventino; Torrens, Hugo
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2005
• Journal volume: 61
• Journal issue: 11
• Pages of publication: m2204 - m2206
• a: 12.5718 ± 0.0006 Å
• b: 19.5538 ± 0.001 Å
• c: 13.3217 ± 0.0007 Å
• α: 90°
• β: 110.547 ± 0.001°
• γ: 90°
• Cell volume: 3066.5 ± 0.3 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0263
• Residual factor for significantly intense reflections: 0.022
• Weighted residual factors for significantly intense reflections: 0.0505
• Weighted residual factors for all reflections included in the refinement: 0.0519
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes