Information card for entry 2209572

Structure parameters

• Common name: Hofmann pyridine complex
• Chemical name: poly[dipyridinemanganese(II)-μ-cyano-nickelate(II)-tri-μ-cyano]
• Formula: C14 H10 Mn N6 Ni
• Calculated formula: C14 H10 Mn N6 Ni
• SMILES: [Mn]1([n]2ccccc2)([n]2ccccc2)([N]#[C])([N]#[C])[N]#C[Ni](C#N)(C#N)C#[N][Mn]([n]2ccccc2)([n]2ccccc2)([N]#[C])([N]#[C])[N]#C[Ni](C#N)(C#N)C#[N]1
• Title of publication: A Hofmann pyridine complex: poly[tetra-μ-cyano-dipyridinemanganese(II)nickel(II)]
• Authors of publication: Hosoya, Kazumasa; Sekiya, Ryo; Nishikiori, Shin-ichi
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2006
• Journal volume: 62
• Journal issue: 7
• Pages of publication: m1627 - m1629
• a: 15.684 ± 0.008 Å
• b: 7.459 ± 0.003 Å
• c: 7.067 ± 0.004 Å
• α: 90°
• β: 104.93 ± 0.02°
• γ: 90°
• Cell volume: 798.8 ± 0.7 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 5
• Space group number: 12
• Hermann-Mauguin space group symbol: C 1 2/m 1
• Hall space group symbol: -C 2y
• Residual factor for all reflections: 0.0835
• Residual factor for significantly intense reflections: 0.0777
• Weighted residual factors for significantly intense reflections: 0.2378
• Weighted residual factors for all reflections included in the refinement: 0.2392
• Goodness-of-fit parameter for all reflections included in the refinement: 1.217
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes