#------------------------------------------------------------------------------
#$Date: 2025-08-19 13:52:15 +0200 (Tue 19 de Aug de 2025) $
#$Revision: 301804 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/51/2215152.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2215152
loop_
_publ_author_name
'Su-Juan Pang'
'Juan Su'
'Qiang Lin'
_publ_section_title
Bis(thiocyanato-κN)tetrakis(1-vinyl-1H-imidazole-κN³)nickel(II)
_journal_coeditor_code           HG2278
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2369
_journal_page_last               m2369
_journal_paper_doi               10.1107/S1600536807039888
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ni (N C S)2 (C5 H6 N2 )4]'
_chemical_formula_moiety         'C22 H24 N10 Ni S2'
_chemical_formula_sum            'C22 H24 N10 Ni S2'
_chemical_formula_weight         551.34
_chemical_name_systematic
;
Bis(thiocyanato-\kN)tetrakis(1-vinyl-1H-imidazole-\kN³)nickel(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                109.46(3)
_cell_angle_beta                 90.16(3)
_cell_angle_gamma                100.16(3)
_cell_formula_units_Z            2
_cell_length_a                   9.6400(19)
_cell_length_b                   10.242(2)
_cell_length_c                   14.705(3)
_cell_measurement_reflns_used    3253
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      14
_cell_measurement_theta_min      4
_cell_volume                     1344.5(6)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  'SHELXTL and local programs'
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Sheldrick, 2001)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART 1K CCD area-detector'
_diffrn_measurement_method       'thin-slice ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0337
_diffrn_reflns_av_sigmaI/netI    0.0729
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            5593
_diffrn_reflns_theta_full        25.96
_diffrn_reflns_theta_max         25.96
_diffrn_reflns_theta_min         1.47
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.907
_exptl_absorpt_correction_T_max  0.8394
_exptl_absorpt_correction_T_min  0.7725
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2004)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.362
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             572
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.656
_refine_diff_density_min         -1.653
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.013
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         5257
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0814
_refine_ls_R_factor_gt           0.0521
_refine_ls_shift/su_max          0.032
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.1152P)²+2.8055P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1435
_refine_ls_wR_factor_ref         0.1983
_reflns_number_gt                3080
_reflns_number_total             5257
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hg2278.cif
_cod_data_source_block           I
_cod_database_code               2215152
_cod_database_fobs_code          2215152
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Ni Ni1 0.5000 0.0000 0.0000 0.0496(4) Uani d S 1
S S1 0.0867(3) 0.2078(3) 0.07754(18) 0.0870(8) Uani d . 1
N N1 0.3250(7) 0.0951(7) 0.0234(4) 0.0646(17) Uani d . 1
N N3 0.3709(9) -0.3102(8) 0.1314(6) 0.080(2) Uani d . 1
N N2 0.4058(6) -0.1414(7) 0.0687(4) 0.0597(16) Uani d . 1
N N5 0.7598(6) 0.2755(6) 0.2474(4) 0.0493(13) Uani d . 1
N N4 0.5948(6) 0.1415(6) 0.1351(4) 0.0530(14) Uani d . 1
C C6 0.3214(10) -0.4777(10) 0.2129(7) 0.085 Uani d . 1
H H6A 0.2422 -0.4401 0.2361 0.102 Uiso calc R 1
H H6B 0.3430 -0.5524 0.2293 0.102 Uiso calc R 1
C C5 0.4024(15) -0.4254(13) 0.1574(9) 0.122(4) Uani d . 1
H H5A 0.4815 -0.4634 0.1345 0.147 Uiso calc R 1
C C3 0.2604(12) -0.2492(12) 0.1510(8) 0.099(3) Uani d . 1
H H3A 0.1837 -0.2739 0.1841 0.118 Uiso calc R 1
C C4 0.2797(9) -0.1443(11) 0.1141(7) 0.086(3) Uani d . 1
H H4A 0.2178 -0.0827 0.1182 0.104 Uiso calc R 1
C C2 0.4563(10) -0.2409(9) 0.0822(7) 0.076(2) Uani d . 1
H H2A 0.5425 -0.2637 0.0607 0.091 Uiso calc R 1
C C11 0.9296(9) 0.4409(8) 0.3719(6) 0.068(2) Uani d . 1
H H11A 0.8578 0.4784 0.4077 0.082 Uiso calc R 1
H H11B 1.0235 0.4767 0.3948 0.082 Uiso calc R 1
C C10 0.8991(8) 0.3395(8) 0.2904(5) 0.0562(18) Uani d . 1
H H10A 0.9740 0.3051 0.2569 0.067 Uiso calc R 1
C C8 0.6330(8) 0.3001(8) 0.2836(5) 0.0569(18) Uani d . 1
H H8A 0.6186 0.3615 0.3441 0.068 Uiso calc R 1
C C9 0.5329(8) 0.2177(8) 0.2143(5) 0.0584(19) Uani d . 1
H H9A 0.4361 0.2131 0.2194 0.070 Uiso calc R 1
C C7 0.7300(8) 0.1789(8) 0.1588(5) 0.0566(18) Uani d . 1
H H7A 0.7984 0.1424 0.1185 0.068 Uiso calc R 1
C C1 0.2269(7) 0.1420(8) 0.0464(5) 0.0520(17) Uani d . 1
Ni Ni2 0.0000 0.0000 0.5000 0.0402(3) Uani d S 1
S S2 0.3353(2) 0.3734(2) 0.4538(2) 0.0853(8) Uani d . 1
N N6 0.1136(6) 0.1787(6) 0.4808(5) 0.0547(15) Uani d . 1
N N8 -0.1142(8) -0.2379(10) 0.2048(5) 0.086(3) Uani d . 1
N N7 -0.0582(6) -0.0859(6) 0.3503(4) 0.0514(14) Uani d . 1
N N10 0.3853(6) -0.1437(6) 0.4179(4) 0.0526(14) Uani d . 1
N N9 0.1789(5) -0.0955(5) 0.4706(4) 0.0459(13) Uani d . 1
C C17 -0.1907(10) -0.4674(10) 0.1355(8) 0.087 Uani d D 1
H H17A -0.1961 -0.4693 0.1982 0.104 Uiso calc R 1
H H17B -0.2163 -0.5504 0.0831 0.104 Uiso calc R 1
C C16 -0.1493(15) -0.3543(14) 0.1217(11) 0.145(5) Uani d D 1
H H16A -0.1424 -0.3481 0.0601 0.174 Uiso calc R 1
C C14 -0.0759(10) -0.1120(11) 0.1937(7) 0.079(3) Uani d . 1
H H14A -0.0746 -0.0929 0.1361 0.095 Uiso calc R 1
C C15 -0.0403(8) -0.0209(9) 0.2817(5) 0.065(2) Uani d . 1
H H15A -0.0074 0.0751 0.2956 0.077 Uiso calc R 1
C C13 -0.1039(9) -0.2177(9) 0.3013(7) 0.074(2) Uani d . 1
H H13A -0.1265 -0.2886 0.3281 0.089 Uiso calc R 1
C C22 0.5619(9) -0.0592(11) 0.3267(7) 0.087(3) Uani d . 1
H H22A 0.5062 -0.0005 0.3147 0.104 Uiso calc R 1
H H22B 0.6506 -0.0615 0.3022 0.104 Uiso calc R 1
C C21 0.5170(8) -0.1359(9) 0.3762(6) 0.067(2) Uani d . 1
H H21A 0.5765 -0.1928 0.3862 0.080 Uiso calc R 1
C C19 0.3321(9) -0.2359(8) 0.4646(6) 0.065(2) Uani d . 1
H H19A 0.3747 -0.3059 0.4733 0.079 Uiso calc R 1
C C20 0.2070(8) -0.2054(8) 0.4953(6) 0.0607(19) Uani d . 1
H H20A 0.1478 -0.2527 0.5287 0.073 Uiso calc R 1
C C18 0.2891(7) -0.0618(7) 0.4241(5) 0.0493(16) Uani d . 1
H H18A 0.2988 0.0108 0.3985 0.059 Uiso calc R 1
C C12 0.2049(7) 0.2587(6) 0.4678(5) 0.0449(15) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N1 Ni1 N1 2_655 . 180.0(3)
N1 Ni1 N2 2_655 . 90.5(3)
N1 Ni1 N2 . . 89.5(3)
N1 Ni1 N2 2_655 2_655 89.5(3)
N1 Ni1 N2 . 2_655 90.5(3)
N2 Ni1 N2 . 2_655 180.0(3)
N1 Ni1 N4 2_655 2_655 89.7(2)
N1 Ni1 N4 . 2_655 90.3(2)
N2 Ni1 N4 . 2_655 90.2(2)
N2 Ni1 N4 2_655 2_655 89.8(2)
N1 Ni1 N4 2_655 . 90.3(2)
N1 Ni1 N4 . . 89.7(2)
N2 Ni1 N4 . . 89.8(2)
N2 Ni1 N4 2_655 . 90.2(2)
N4 Ni1 N4 2_655 . 180.0(2)
C1 N1 Ni1 . . 171.2(7)
C3 N3 C2 . . 107.0(8)
C3 N3 C5 . . 128.4(10)
C2 N3 C5 . . 124.6(10)
C2 N2 C4 . . 103.6(8)
C2 N2 Ni1 . . 127.3(6)
C4 N2 Ni1 . . 129.0(6)
C7 N5 C8 . . 106.2(6)
C7 N5 C10 . . 124.8(6)
C8 N5 C10 . . 128.9(6)
C7 N4 C9 . . 104.8(6)
C7 N4 Ni1 . . 125.7(5)
C9 N4 Ni1 . . 129.4(5)
C5 C6 H6A . . 120.0
C5 C6 H6B . . 120.0
H6A C6 H6B . . 120.0
C6 C5 N3 . . 120.9(13)
C6 C5 H5A . . 119.6
N3 C5 H5A . . 119.6
N3 C3 C4 . . 106.6(9)
N3 C3 H3A . . 126.7
C4 C3 H3A . . 126.7
C3 C4 N2 . . 109.9(9)
C3 C4 H4A . . 125.0
N2 C4 H4A . . 125.0
N2 C2 N3 . . 112.8(9)
N2 C2 H2A . . 123.6
N3 C2 H2A . . 123.6
C10 C11 H11A . . 120.0
C10 C11 H11B . . 120.0
H11A C11 H11B . . 120.0
C11 C10 N5 . . 125.5(7)
C11 C10 H10A . . 117.3
N5 C10 H10A . . 117.3
C9 C8 N5 . . 106.4(6)
C9 C8 H8A . . 126.8
N5 C8 H8A . . 126.8
C8 C9 N4 . . 109.9(7)
C8 C9 H9A . . 125.0
N4 C9 H9A . . 125.0
N4 C7 N5 . . 112.7(6)
N4 C7 H7A . . 123.7
N5 C7 H7A . . 123.7
N1 C1 S1 . . 179.2(7)
N6 Ni2 N6 2_556 . 180.00(18)
N6 Ni2 N9 2_556 . 90.4(2)
N6 Ni2 N9 . . 89.6(2)
N6 Ni2 N9 2_556 2_556 89.6(2)
N6 Ni2 N9 . 2_556 90.4(2)
N9 Ni2 N9 . 2_556 180.0(3)
N6 Ni2 N7 2_556 . 90.2(2)
N6 Ni2 N7 . . 89.8(2)
N9 Ni2 N7 . . 87.7(2)
N9 Ni2 N7 2_556 . 92.3(2)
N6 Ni2 N7 2_556 2_556 89.8(2)
N6 Ni2 N7 . 2_556 90.2(2)
N9 Ni2 N7 . 2_556 92.3(2)
N9 Ni2 N7 2_556 2_556 87.7(2)
N7 Ni2 N7 . 2_556 180.0000(10)
C12 N6 Ni2 . . 162.1(6)
C14 N8 C13 . . 107.9(7)
C14 N8 C16 . . 117.1(9)
C13 N8 C16 . . 134.9(10)
C13 N7 C15 . . 104.7(7)
C13 N7 Ni2 . . 126.1(6)
C15 N7 Ni2 . . 128.7(5)
C18 N10 C19 . . 105.5(6)
C18 N10 C21 . . 128.4(7)
C19 N10 C21 . . 126.1(7)
C18 N9 C20 . . 104.6(6)
C18 N9 Ni2 . . 127.7(5)
C20 N9 Ni2 . . 127.8(5)
C16 C17 H17A . . 120.0
C16 C17 H17B . . 120.0
H17A C17 H17B . . 120.0
C17 C16 N8 . . 114.9(13)
C17 C16 H16A . . 122.5
N8 C16 H16A . . 122.6
C15 C14 N8 . . 105.5(8)
C15 C14 H14A . . 127.2
N8 C14 H14A . . 127.2
C14 C15 N7 . . 111.5(8)
C14 C15 H15A . . 124.3
N7 C15 H15A . . 124.3
N7 C13 N8 . . 110.4(8)
N7 C13 H13A . . 124.8
N8 C13 H13A . . 124.8
C21 C22 H22A . . 120.0
C21 C22 H22B . . 120.0
H22A C22 H22B . . 120.0
C22 C21 N10 . . 126.4(9)
C22 C21 H21A . . 116.8
N10 C21 H21A . . 116.8
C20 C19 N10 . . 106.9(6)
C20 C19 H19A . . 126.6
N10 C19 H19A . . 126.6
C19 C20 N9 . . 110.4(7)
C19 C20 H20A . . 124.8
N9 C20 H20A . . 124.8
N9 C18 N10 . . 112.6(6)
N9 C18 H18A . . 123.7
N10 C18 H18A . . 123.7
N6 C12 S2 . . 177.9(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ni1 N1 2_655 2.067(6)
Ni1 N1 . 2.067(6)
Ni1 N2 . 2.111(6)
Ni1 N2 2_655 2.111(6)
Ni1 N4 2_655 2.118(6)
Ni1 N4 . 2.118(6)
S1 C1 . 1.615(7)
N1 C1 . 1.138(9)
N3 C3 . 1.313(13)
N3 C2 . 1.358(11)
N3 C5 . 1.434(14)
N2 C2 . 1.276(10)
N2 C4 . 1.388(10)
N5 C7 . 1.341(9)
N5 C8 . 1.366(9)
N5 C10 . 1.429(9)
N4 C7 . 1.303(8)
N4 C9 . 1.373(9)
C6 C5 . 1.308(14)
C6 H6A . 0.9300
C6 H6B . 0.9300
C5 H5A . 0.9300
C3 C4 . 1.343(13)
C3 H3A . 0.9300
C4 H4A . 0.9300
C2 H2A . 0.9300
C11 C10 . 1.288(10)
C11 H11A . 0.9300
C11 H11B . 0.9300
C10 H10A . 0.9300
C8 C9 . 1.348(10)
C8 H8A . 0.9300
C9 H9A . 0.9300
C7 H7A . 0.9300
Ni2 N6 2_556 2.065(5)
Ni2 N6 . 2.065(5)
Ni2 N9 . 2.106(5)
Ni2 N9 2_556 2.106(5)
Ni2 N7 . 2.113(6)
Ni2 N7 2_556 2.113(6)
S2 C12 . 1.626(7)
N6 C12 . 1.155(8)
N8 C14 . 1.341(12)
N8 C13 . 1.366(11)
N8 C16 . 1.383(15)
N7 C13 . 1.294(10)
N7 C15 . 1.378(9)
N10 C18 . 1.340(9)
N10 C19 . 1.375(9)
N10 C21 . 1.413(9)
N9 C18 . 1.321(8)
N9 C20 . 1.361(8)
C17 C16 . 1.240(19)
C17 H17A . 0.9300
C17 H17B . 0.9300
C16 H16A . 0.9300
C14 C15 . 1.320(11)
C14 H14A . 0.9300
C15 H15A . 0.9300
C13 H13A . 0.9300
C22 C21 . 1.264(12)
C22 H22A . 0.9300
C22 H22B . 0.9300
C21 H21A . 0.9300
C19 C20 . 1.340(10)
C19 H19A . 0.9300
C20 H20A . 0.9300
C18 H18A . 0.9300
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C7 H7A S1 1_655 0.93 2.86 3.638(8) 142 y
C10 H10A S1 1_655 0.93 2.79 3.601(8) 146 y
C16 H16A S1 2_555 0.93 2.85 3.717(18) 155 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N1 Ni1 N2 C2 2_655 -0.4(7)
N1 Ni1 N2 C2 . 179.6(7)
N4 Ni1 N2 C2 2_655 89.2(7)
N4 Ni1 N2 C2 . -90.8(7)
N1 Ni1 N2 C4 2_655 175.8(7)
N1 Ni1 N2 C4 . -4.2(7)
N4 Ni1 N2 C4 2_655 -94.6(7)
N4 Ni1 N2 C4 . 85.4(7)
N1 Ni1 N4 C7 2_655 25.0(7)
N1 Ni1 N4 C7 . -155.0(7)
N2 Ni1 N4 C7 . 115.5(6)
N2 Ni1 N4 C7 2_655 -64.5(6)
N1 Ni1 N4 C9 . 22.0(7)
N2 Ni1 N4 C9 . -67.5(6)
N2 Ni1 N4 C9 2_655 112.5(6)
C3 N3 C5 C6 . -4.9(18)
C2 N3 C5 C6 . 173.2(10)
C2 N3 C3 C4 . -0.1(11)
C5 N3 C3 C4 . 178.3(10)
N3 C3 C4 N2 . 0.8(12)
C2 N2 C4 C3 . -1.3(11)
Ni1 N2 C4 C3 . -178.2(6)
C4 N2 C2 N3 . 1.2(10)
Ni1 N2 C2 N3 . 178.2(5)
C3 N3 C2 N2 . -0.8(11)
C5 N3 C2 N2 . -179.3(9)
C7 N5 C10 C11 . 173.7(8)
C8 N5 C10 C11 . -4.3(12)
C7 N5 C8 C9 . -0.6(8)
C10 N5 C8 C9 . 177.6(7)
N5 C8 C9 N4 . 0.1(9)
C7 N4 C9 C8 . 0.4(9)
Ni1 N4 C9 C8 . -177.1(5)
C9 N4 C7 N5 . -0.9(9)
Ni1 N4 C7 N5 . 176.7(5)
C8 N5 C7 N4 . 1.0(9)
C10 N5 C7 N4 . -177.4(6)
N9 Ni2 N6 C12 . -4.8(19)
N9 Ni2 N6 C12 2_556 175.2(19)
N7 Ni2 N6 C12 . -92.5(19)
N7 Ni2 N6 C12 2_556 87.5(19)
N6 Ni2 N7 C13 2_556 -19.3(7)
N6 Ni2 N7 C13 . 160.7(7)
N9 Ni2 N7 C13 . 71.0(7)
N9 Ni2 N7 C13 2_556 -109.0(7)
N6 Ni2 N7 C15 2_556 169.7(6)
N6 Ni2 N7 C15 . -10.3(6)
N9 Ni2 N7 C15 . -100.0(6)
N9 Ni2 N7 C15 2_556 80.0(6)
N6 Ni2 N9 C18 2_556 159.1(6)
N6 Ni2 N9 C18 . -20.9(6)
N7 Ni2 N9 C18 . 69.0(6)
N7 Ni2 N9 C18 2_556 -111.0(6)
N6 Ni2 N9 C20 2_556 -21.0(6)
N6 Ni2 N9 C20 . 159.0(6)
N7 Ni2 N9 C20 . -111.1(6)
N7 Ni2 N9 C20 2_556 68.9(6)
C14 N8 C16 C17 . -176.6(11)
C13 N8 C16 C17 . 6(2)
C13 N8 C14 C15 . 1.6(10)
C16 N8 C14 C15 . -176.5(9)
N8 C14 C15 N7 . -1.4(10)
C13 N7 C15 C14 . 0.6(9)
Ni2 N7 C15 C14 . 173.1(6)
C15 N7 C13 N8 . 0.5(9)
Ni2 N7 C13 N8 . -172.3(5)
C14 N8 C13 N7 . -1.4(10)
C16 N8 C13 N7 . 176.3(11)
C18 N10 C21 C22 . -8.8(14)
C19 N10 C21 C22 . 174.1(9)
C18 N10 C19 C20 . 0.6(8)
C21 N10 C19 C20 . 178.3(7)
N10 C19 C20 N9 . -0.7(9)
C18 N9 C20 C19 . 0.4(8)
Ni2 N9 C20 C19 . -179.5(5)
C20 N9 C18 N10 . 0.0(8)
Ni2 N9 C18 N10 . 179.9(4)
C19 N10 C18 N9 . -0.4(8)
C21 N10 C18 N9 . -178.0(6)
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1 PubChem 139072947
