Information card for entry 2219276

Structure parameters

• Chemical name: [μ-Diphenylphosphanido-κ^2^<i>P</i>:<i>P</i>']bis[(2,6-diphenylpyridine- κ^3^<i>C</i>^2^,<i>N</i>,<i>C</i>^2'^)gold(III)] perchlorate acetonitrile solvate
• Formula: C48 H35 Au2 Cl N3 O4 P
• Calculated formula: C48 H35 Au2 Cl N3 O4 P
• SMILES: [Au]12(c3ccccc3c3[n]1c(ccc3)c1ccccc21)[P]([Au]12c3ccccc3c3[n]1c(ccc3)c1ccccc21)(c1ccccc1)c1ccccc1.Cl(=O)(=O)(=O)[O-].N#CC
• Title of publication: (μ-Diphenylphosphanido-κ^2^<i>P</i>:<i>P</i>')bis[2,2'-(pyridine-2,6-diyl)diphenyl-κ^3^<i>C</i>^1^,<i>N</i>,<i>C</i>^1'^)gold(III)] perchlorate acetonitrile solvate
• Authors of publication: Li, Xin-Sheng; Mo, Juan; Zhang, Su-Mei; Yuan, Li; Liu, Jian-Hua
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2008
• Journal volume: 64
• Journal issue: 9
• Pages of publication: m1126 - m1127
• a: 10.0612 ± 0.0016 Å
• b: 13.526 ± 0.002 Å
• c: 29.64 ± 0.005 Å
• α: 90°
• β: 98.828 ± 0.004°
• γ: 90°
• Cell volume: 3985.9 ± 1.1 ų
• Cell temperature: 113 ± 2 K
• Ambient diffraction temperature: 113 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0351
• Residual factor for significantly intense reflections: 0.0282
• Weighted residual factors for significantly intense reflections: 0.0546
• Weighted residual factors for all reflections included in the refinement: 0.0572
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes