Information card for entry 2232930

Structure parameters

• Chemical name: Bis[μ~2~-bis(diphenylphosphanyl)methane-κ^2^<i>P</i>:<i>P</i>']bis(μ~4~- diphenylphosphinato-κ^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis(μ~2~- trifluoroacetato-κ^2^<i>O</i>:<i>O</i>')tetrasilver(I) acetonitrile disolvate
• Formula: C82 H70 Ag4 F6 N2 O8 P6
• Calculated formula: C82 H70 Ag4 F6 N2 O8 P6
• SMILES: [Ag]123[P](c4ccccc4)(c4ccccc4)C[P](c4ccccc4)(c4ccccc4)[Ag]45[O]=C(O[Ag]67[O]4P(=[O]3[Ag]([O]2=P([O]56)(c2ccccc2)c2ccccc2)([O]=C(O1)C(F)(F)F)[P](C[P]7(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C(F)(F)F.N#CC.N#CC
• Title of publication: Bis[μ~2~-bis(diphenylphosphanyl)methane-κ^2^<i>P</i>:<i>P</i>']bis(μ~4~-diphenylphosphinato-κ^4^<i>O</i>:<i>O</i>:<i>O</i>':<i>O</i>')bis(μ~2~-trifluoroacetato-κ^2^<i>O</i>:<i>O</i>')tetrasilver(I) acetonitrile disolvate
• Authors of publication: Huang, Li-Li; Jia, Chen; Tang, Li-Ping; Jing, Bai; Deng, Qi-Hua
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2011
• Journal volume: 67
• Journal issue: 12
• Pages of publication: m1677 - m1678
• a: 11.724 ± 0.005 Å
• b: 14.777 ± 0.006 Å
• c: 24.183 ± 0.01 Å
• α: 90°
• β: 102.254 ± 0.005°
• γ: 90°
• Cell volume: 4094 ± 3 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0571
• Residual factor for significantly intense reflections: 0.0455
• Weighted residual factors for significantly intense reflections: 0.1096
• Weighted residual factors for all reflections included in the refinement: 0.1167
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes