Information card for entry 2233875

Structure parameters

• Chemical name: (+)-Chlorido[(1,2,3,4-η;κ<i>P</i>^2'^)-2'-diphenylphosphanyl-2- diphenylphosphoryl-1,1'-binaphthyl]rhodium(I) methanol monosolvate
• Formula: C45 H36 Cl O2 P2 Rh
• Calculated formula: C45 H36 Cl O2 P2 Rh
• SMILES: [Rh]1234(Cl)[P](c5c([C]64=[C]1(P(=O)(c1ccccc1)c1ccccc1)[CH]2=[CH]3c1ccccc61)c1ccccc1cc5)(c1ccccc1)c1ccccc1.OC
• Title of publication: (+)-Chlorido[(1,2,3,4-η;κ<i>P</i>^2'^)-2'-diphenylphosphanyl-2-diphenylphosphoryl-1,1'-binaphthyl]rhodium(I) methanol monosolvate
• Authors of publication: Meissner, Antje; Selle, Carmen; Drexler, Hans-Joachim; Heller, Detlef
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2012
• Journal volume: 68
• Journal issue: 3
• Pages of publication: m259
• a: 9.2108 ± 0.0018 Å
• b: 9.7453 ± 0.0019 Å
• c: 11.354 ± 0.002 Å
• α: 103.01 ± 0.03°
• β: 104.59 ± 0.03°
• γ: 105.09 ± 0.03°
• Cell volume: 905 ± 0.4 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 6
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0305
• Residual factor for significantly intense reflections: 0.0266
• Weighted residual factors for significantly intense reflections: 0.0428
• Weighted residual factors for all reflections included in the refinement: 0.0432
• Goodness-of-fit parameter for all reflections included in the refinement: 0.955
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes