Information card for entry 2236466

Structure parameters

• Chemical name: Di-μ-carbonyl-bis[bis(triphenylphosphane)rhodium(0)](<i>Rh</i>—<i>Rh</i>) acetone disolvate
• Formula: C80 H72 O4 P4 Rh2
• Calculated formula: C74 H60 O2 P4 Rh2
• SMILES: c1(ccccc1)[P](c1ccccc1)(c1ccccc1)[Rh]12([P](c3ccccc3)(c3ccccc3)c3ccccc3)C(=O)[Rh]2([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)C1=O
• Title of publication: Di-μ-carbonyl-bis[bis(triphenylphosphane)rhodium(0)](<i>Rh</i>—<i>Rh</i>) acetone disolvate
• Authors of publication: Gueorguieva, Petia G.; Laneman, Scott A.; Stanley, George G.; Fronczek, Frank R.; Watkins, Steven F.
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2012
• Journal volume: 68
• Journal issue: 11
• Pages of publication: m1408 - m1409
• a: 23.535 ± 0.003 Å
• b: 13.0758 ± 0.0011 Å
• c: 24.65 ± 0.002 Å
• α: 90°
• β: 115.67 ± 0.02°
• γ: 90°
• Cell volume: 6837.1 ± 1.6 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Cell measurement pressure: 101.3 kPa
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 0.0324
• Weighted residual factors for all reflections included in the refinement: 0.0823
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes