Information card for entry 2242993

Structure parameters

• Chemical name: <i>catena</i>-Poly[[chloridoaluminate(III)]-tri-μ-chlorido-4':1κ^2^<i>Cl</i>,1:2κ^4^<i>Cl</i>-[(η^6^-1,2,3,4-tetramethylbenzene)tin(II)]-di-μ-chlorido-2:3κ^4^<i>Cl</i>-[(η^6^-1,2,3,4-tetramethylbenzene)tin(II)]-di-μ-chlorido-3:4κ^4^<i>Cl</i>-[chloridoaluminate(III)]-μ-chlorido-4:1'κ^2^<i>Cl</i>]
• Formula: C20 H28 Al2 Cl10 Sn2
• Calculated formula: C20 H28 Al2 Cl10 Sn2
• SMILES: [Sn]1[Cl][Sn][Cl]1.[Cl-][Al](Cl)(Cl)Cl.[Cl-][Al](Cl)(Cl)Cl.c1cc(c(c(c1C)C)C)C.c1cc(c(c(c1C)C)C)C
• Title of publication: Synthesis, detailed geometric analysis and bond-valence method evaluation of the strength of π-arene bonding of two isotypic cationic prehnitene tin(II) complexes: [{1,2,3,4-(CH~3~)~4~C~6~H~2~}~2~Sn~2~Cl~2~][<i>M</i>Cl~4~]~2~ (<i>M</i> = Al and Ga)
• Authors of publication: Merkelbach, Johannes; Frank, Walter
• Journal of publication: Acta Crystallographica Section E
• Year of publication: 2019
• Journal volume: 75
• Journal issue: 7
• Pages of publication: 1051 - 1056
• a: 8.7512 ± 0.0005 Å
• b: 9.1357 ± 0.0006 Å
• c: 11.2803 ± 0.0007 Å
• α: 85.524 ± 0.005°
• β: 72.769 ± 0.005°
• γ: 86.926 ± 0.005°
• Cell volume: 858.3 ± 0.09 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0312
• Residual factor for significantly intense reflections: 0.0276
• Weighted residual factors for significantly intense reflections: 0.0563
• Weighted residual factors for all reflections included in the refinement: 0.0575
• Goodness-of-fit parameter for all reflections included in the refinement: 1.243
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes