Information card for entry 2312100

Structure parameters

• Common name: Hexachloridotetrakis{10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-\ silatriptycene}nickeldiplatinum–dichloromethane–ethanol (1/5/20), [NiPt~2Cl~6(TRIPPy)~4]
• Chemical name: <i>catena</i>-Poly[[[dichloridonickel(II)]-bis{μ-10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-silatriptycene}-bis[dichloridoplatinum(II)]-bis{μ-10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-silatriptycene}] dichloromethane pentasolvate ethanol icosasolvate]
• Formula: C161 H210 Cl16 N4 Ni O20 P4 Pt2 Si4
• Calculated formula: C116 H80 Cl6 N4 Ni P4 Pt2 Si4
• Title of publication: The heterometallic one-dimensional solvated coordination polymer [NiPt₂Cl₆(TRIP-Py)₄]_n.
• Authors of publication: Gildenast, Hans; Gruszien, Lukas; Englert, Ulli
• Journal of publication: Acta crystallographica. Section C, Structural chemistry
• Year of publication: 2023
• Journal volume: 79
• Journal issue: Pt 4
• Pages of publication: 118 - 124
• a: 12.702 ± 0.007 Å
• b: 19.372 ± 0.01 Å
• c: 20.34 ± 0.007 Å
• α: 71.313 ± 0.007°
• β: 81.809 ± 0.013°
• γ: 78.917 ± 0.019°
• Cell volume: 4635 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0481
• Residual factor for significantly intense reflections: 0.0359
• Weighted residual factors for significantly intense reflections: 0.1021
• Weighted residual factors for all reflections included in the refinement: 0.1077
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.5 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: Yes